氫化亞銅

氫化亞銅
	IUPAC名; 氫化亞銅
識別
CAS號	13517-00-5
PubChem	3335333
ChemSpider	2582262
SMILES	[CuH];
性質
化學式	HCu
摩爾質量	64.55 g·mol−1
熔點	100 °C（212 °F；373 K）
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

氫化亞銅（化學式：CuH）是銅的二元氫化物。Cu-H鍵很弱因此這種化合物是不穩定的。^[2]^[3]硫酸銅與次磷酸鈉在少量硫酸存在的條件下反應得到這種紅色沉澱。它受熱就分解為金屬銅和氫氣。X射線衍射實驗已經測定了它的晶體結構。^[4]它與三苯基膦的加合物是有機化學中的斯瑞克試劑（英語：Stryker's reagent）。

參考資料[編輯]

^ Fitzsimons, Nuala P.; Jones, William; Herley, Patrick J. Studies of copper hydride. Part 1.—Synthesis and solid-state stability. Journal of the Chemical Society, Faraday Transactions. 1 January 1995, 91 (4): 713–718. doi:10.1039/FT9959100713.
^ Hydrides of the Main-Group Metals: New Variations on an Old Theme Simon Aldridge , Anthony J. Downs Chem. Rev., 2001, 101 (11), pp 3305–3366 doi:10.1021/cr960151d
^ Laboratory Methods of Inorganic Chemistry Wilhelm Biltz Heinrich
^ The crystal structure of copper hydride J. A. Goedkoop and A. F. Andresen Acta Cryst. (1955). 8, 118-119 doi:10.1107/S0365110X55000480

[Fitzsimons1995-1] Fitzsimons, Nuala P.; Jones, William; Herley, Patrick J. Studies of copper hydride. Part 1.—Synthesis and solid-state stability. Journal of the Chemical Society, Faraday Transactions. 1 January 1995, 91 (4): 713–718. doi:10.1039/FT9959100713.

[2] Hydrides of the Main-Group Metals: New Variations on an Old Theme Simon Aldridge , Anthony J. Downs Chem. Rev., 2001, 101 (11), pp 3305–3366 doi:10.1021/cr960151d

[3] Laboratory Methods of Inorganic Chemistry Wilhelm Biltz Heinrich

[4] The crystal structure of copper hydride J. A. Goedkoop and A. F. Andresen Acta Cryst. (1955). 8, 118-119 doi:10.1107/S0365110X55000480

[1]

[2]

[3]

[4]