五甲基钽

五甲基钽是一种有机钽化合物（英语：Organotantalum chemistry），化学式为Ta(CH₃)₅，它有可能在熔化时爆炸。^[4]它可由五氯化钽和二甲基锌的反应制得。^[5]它可以和甲基锂反应，生成[Ta(CH₃)₆]⁻或[Ta(CH₃)₇]²⁻。^[6]它和一氧化氮反应，得到二聚体{TaMe₃[ON(CH₃)NO]₂}₂。^[7]

参考文献[编辑]

^ Yaws, Carl L. The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals: Physical Properties for More Than 54,000 Organic and Inorganic Chemical Compounds, Coverage for C1 to C100 Organics and Ac to Zr Inorganics. Gulf Professional Publishing. 2015: 87 [2020-12-09]. ISBN 9780128011461. （原始内容存档于2016-08-07）（英语）.
^ Adedeji, Festus A.; Connor, Joseph A.; Skinner, Henry A.; Galyer, Lee; Wilkinson, Geoffrey. Heat of formation of pentamethylantalum and hexamethyltungsten. Journal of the Chemical Society, Chemical Communications. 1976, (5): 159. doi:10.1039/C39760000159.
^ Pentamethyl tantalum. webbook.nist.gov. [2020-12-09]. （原始内容存档于2020-12-09）（英语）.
^ Urben, Peter. Bretherick's Handbook of Reactive Chemical Hazards. Academic Press. 2013: 744. ISBN 9780080523408 （英语）.
^ Herrmann, W. A. Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 7, 1997: Volume 7: Transition Metals. Georg Thieme Verlag. 2014: 160–161. ISBN 9783131794710 （德语）.
^ Schrock, R. R.; Meakin, P. Pentamethyl complexes of niobium and tantalum. Journal of the American Chemical Society. August 1974, 96 (16): 5288–5290. doi:10.1021/ja00823a064.
^ Middleton, A. Robert; Wilkinson, Geoffrey. Interaction of nitric oxide with paramagnetic and diamagnetic alkyls of titanium, zirconium, vanadium, niobium, and tantalum. Journal of the Chemical Society, Dalton Transactions. 1980, (10): 1888. doi:10.1039/DT9800001888.