六氟砷酸五氟合氙(VI)

六氟砷酸五氟合氙(VI)
识别
CAS号	20328-94-3
SMILES	F[Xe+](F)(F)(F)F.F[As-](F)(F)(F)(F)F;
性质
化学式	AsF11Xe
摩尔质量	415.2 g·mol−1
密度	3.51 g/cm3
熔点	130.5 °C
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

六氟砷酸五氟合氙(VI)是一种无机化合物，化学式 [XeF₅]⁺[AsF₆]^-，由尼尔·巴特利特的团队于1969年首次合成。^[2]。

制备[编辑]

在通过六氟化物和氙的反应成功合成XePtF
6^[3]、XeRhF
6^[4]和XeRuF
6^[5]后，巴特利特发现这种方法只能获得少数金属的化合物，其它金属要么不形成六氟化物，要么氧化电位太低。^[6]他们必须找到另一种合成方法——答案就是使用适当的氙的氟化物和金属五氟化物来合成氙化合物。六氟砷酸五氟合氙(VI)可以由六氟化氙和五氟化砷在五氟化溴溶液中反应而成：^[2]^[7]^[8]

XeF₆ + AsF₅ → [XeF₅]⁺[AsF₆]^-

性质[编辑]

六氟砷酸五氟合氙(VI)是白色晶体，密度 3.51 g/cm³，熔点 130.5 °C，属于单斜晶系。^[1]

参考资料[编辑]

^ ^1.0 ^1.1 ^1.2 Lide, David. CRC handbook of chemistry and physics : a ready-reference book of chemical and physical data. Boca Raton, Fla. London: CRC. 2007: 4-98. ISBN 978-0-8493-0488-0. OCLC 85691089.
^ ^2.0 ^2.1 Sladky, F. O.; Bulliner, P. A.; Bartlett, Neil. Xenon difluoride as a fluoride ion donor. Evidence for the salts [Xe2F3]+[MF6]–,[XeF]+[MF6]–and [XeF]+[M2F11]–. J. Chem. Soc. A (Royal Society of Chemistry (RSC)). 1969, 0 (0): 2179–2188. ISSN 0022-4944. doi:10.1039/j19690002179.
^ Proceedings of the Chemical Society. June 1962. Proceedings of the Chemical Society (Royal Society of Chemistry (RSC)). 1962, (June): 197. ISSN 0369-8718. doi:10.1039/ps9620000197.
^ Chernick, C. L.; Claassen, H. H.; Fields, P. R.; Hyman, H. H.; Malm, J. G.; Manning, W. M.; Matheson, M. S.; Quarterman, L. A.; Schreiner, F.; Selig, H. H.; Sheft, I.; Siegel, S.; Sloth, E. N.; Stein, L.; Studier, M. H.; Weeks, J. L.; Zirin, M. H. Fluorine Compounds of Xenon and Radon. Science (American Association for the Advancement of Science (AAAS)). 1962-10-12, 138 (3537): 136–138. ISSN 0036-8075. doi:10.1126/science.138.3537.136.
^ Hyman, H.H. Noble Gas Compounds. Chicago: Chicago University Press. 1963: 23–30.
^ Tamadon, Farhad; Seidel, Stefan; Seppelt, Konrad. Reactions of Xenon with Iridiumand Osmiumhexafluoride (PDF). Acta Chimica Slovenica. 2013, 60: 491–494 [2022-02-26]. ISSN 1318-0207. （原始内容 (PDF)存档于2022-02-26）.
^ Horn, Hans-Georg; Hein, Hiltrud. Buschbeck, Karl-Christian; Lippert, Walter; Slawisch, Adolf , 编. Edelgasverbindungen. Berlin, Heidelberg: Springer Berlin Heidelberg. 1970. ISBN 978-3-662-11601-2. doi:10.1007/978-3-662-11600-5.
^ Bartlett, Neil. The oxidation of oxygen and related chemistry : selected papers of Neil Bartlett. Singapore River Edge, NJ: World Scientific. 2001. ISBN 981-02-2775-2. OCLC 505149557.

[CRC-1] 1.0 ^1.1 ^1.2 Lide, David. CRC handbook of chemistry and physics : a ready-reference book of chemical and physical data. Boca Raton, Fla. London: CRC. 2007: 4-98. ISBN 978-0-8493-0488-0. OCLC 85691089.

[Bartlett_1969-2] 2.0 ^2.1 Sladky, F. O.; Bulliner, P. A.; Bartlett, Neil. Xenon difluoride as a fluoride ion donor. Evidence for the salts [Xe2F3]+[MF6]–,[XeF]+[MF6]–and [XeF]+[M2F11]–. J. Chem. Soc. A (Royal Society of Chemistry (RSC)). 1969, 0 (0): 2179–2188. ISSN 0022-4944. doi:10.1039/j19690002179.

[Bartlett_1962-3] Proceedings of the Chemical Society. June 1962. Proceedings of the Chemical Society (Royal Society of Chemistry (RSC)). 1962, (June): 197. ISSN 0369-8718. doi:10.1039/ps9620000197.

[Chernick_1962-4] Chernick, C. L.; Claassen, H. H.; Fields, P. R.; Hyman, H. H.; Malm, J. G.; Manning, W. M.; Matheson, M. S.; Quarterman, L. A.; Schreiner, F.; Selig, H. H.; Sheft, I.; Siegel, S.; Sloth, E. N.; Stein, L.; Studier, M. H.; Weeks, J. L.; Zirin, M. H. Fluorine Compounds of Xenon and Radon. Science (American Association for the Advancement of Science (AAAS)). 1962-10-12, 138 (3537): 136–138. ISSN 0036-8075. doi:10.1126/science.138.3537.136.

[Bartlett_1963-5] Hyman, H.H. Noble Gas Compounds. Chicago: Chicago University Press. 1963: 23–30.

[Tamadon-6] Tamadon, Farhad; Seidel, Stefan; Seppelt, Konrad. Reactions of Xenon with Iridiumand Osmiumhexafluoride (PDF). Acta Chimica Slovenica. 2013, 60: 491–494 [2022-02-26]. ISSN 1318-0207. （原始内容 (PDF)存档于2022-02-26）.

[Gmelins-7] Horn, Hans-Georg; Hein, Hiltrud. Buschbeck, Karl-Christian; Lippert, Walter; Slawisch, Adolf , 编. Edelgasverbindungen. Berlin, Heidelberg: Springer Berlin Heidelberg. 1970. ISBN 978-3-662-11601-2. doi:10.1007/978-3-662-11600-5.

[Bartlett_2001-8] Bartlett, Neil. The oxidation of oxygen and related chemistry : selected papers of Neil Bartlett. Singapore River Edge, NJ: World Scientific. 2001. ISBN 981-02-2775-2. OCLC 505149557.

[1]

[2]

[3]

[4]

[5]

[6]

[7]

[8]