氟三碘甲烷

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氟三碘甲烷
IUPAC名
Fluoro(triiodo)methane
别名 Fluorotriiodomethane
识别
CAS号 1495-49-4  ✓
PubChem 23510639
ChemSpider 11570071
SMILES
InChI
InChIKey GXKSSISYTXERRQ-UHFFFAOYSA-N
性质
化学式 CFI3
摩尔质量 411.72 g·mol−1
密度 3.847±0.06 g·cm−3[1]
沸点 204.5±8.0 °C[1]
溶解性 0.04 g/100 mL[1]
若非注明,所有数据均出自一般条件(25 ℃,100 kPa)下。

氟三碘甲烷是一种甲烷衍生化合物,化学式CFI3[2][3][4]它可以在三氟碘甲烷辐解中产生,产生机理源自于反应中生成的:CFI和I2或CF3I的反应。[5][6]它的生成热−ΔHfθ为−2 kcal·mol−1,而CI3X的氯代或溴代物的值要更负。[7]

参考文献[编辑]

  1. ^ 1.0 1.1 1.2 Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-3-23]
  2. ^ fluorotriiodomethane. NIST. wtt-pro.nist.gov. [7 June 2017]. 
  3. ^ fluorotriiodomethane. webbook.nist.gov. [7 June 2017]. 
  4. ^ Gurvich, L. V.; Veyts, I. Thermodynamic Properties of Individual Substances: Elements and Compounds. CRC Press. September 1, 1990: 185. ISBN 9780891165330. 
  5. ^ Nozomi Nakayama, Elizabeth E. Ferrenz, Denise R. Ostling, Andrea S. Nichols, Janelle F. Faulk, Christopher R. Arumainayagam. Surface Chemistry and Radiation Chemistry of Trifluoroiodomethane (CF 3 I) on Mo(110). The Journal of Physical Chemistry B. 2004-4, 108 (13): 4080–4085 [2019-03-23]. ISSN 1520-6106. doi:10.1021/jp0310192 (英语). 
  6. ^ Mahesh Rajappan, Lin L Zhu, Jizhou Wang, Graeme Gardner, Kevin Bu, Huiliang Mai, Madeleine Laupheimer, Yomay Shyur, Nuriesya S Abu Bakar, Samantha K Skinner-Hall, Christina Kim, Jaclyn M Haskins, Christopher R Arumainayagam. The role of low-energy electrons in the high-energy radiolysis of condensed CF 3 I. Journal of Physics: Condensed Matter. 2010-03-03, 22 (8): 084006 [2019-03-23]. ISSN 0953-8984. doi:10.1088/0953-8984/22/8/084006. 
  7. ^ Maslov, P. G.; Maslov, Yu. P. Heats of formation of halogen derivatives of methane and ethylene. Khimiya i Tekhnologiya Topliv i Masel, 1958. 3 (10): 50-55, ISSN 0023-1169.

拓展阅读[编辑]

  • Sladkov, I. B.; Bogacheva, A. V. Critical parameters of mixed halides of carbon. Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1991. 64 (11): 2435-2437. ISSN: 0044-4618.