磷化镨 是镨 和磷 的无机化合物 ，化学式为PrP。[2] [3] [4]
在碘蒸汽下将镨金属和磷共热：[5]
Pr
+
P
⟶
PrP
{\displaystyle {\ce {Pr + P -> PrP}}}
物理性质 [ 编辑 ] 磷化镨会形成立方晶体，空间群为F m3m ，晶格常数为a = 0.5872 nm，Z = 4，结构类似氯化钠 NaCl。[6] [7]
这个化合物在3120 °C均匀融化。
参考文献 [ 编辑 ]
^ Rowley, Adrian T.; Parkin, Ivan P. Convenient synthesis of lanthanide and mixed lanthanide phosphides by solid-state routes involving sodium phosphide. Journal of Materials Chemistry (Royal Society of Chemistry (RSC)). 1993, 3 (7): 689. ISSN 0959-9428 doi:10.1039/jm9930300689 ^ Praseodymium Phosphide . American Elements . [14 December 2021] . （原始内容 存档于2021-12-14） （英语） . ^ Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Cumulative Supplement to the Initial Inventory: User Guide and Indices . United States Environmental Protection Agency . 1980: 252 [14 December 2021] （英语） . ^ O'Bannon, Loran. Dictionary of Ceramic Science and Engineering . Springer Science & Business Media . 6 December 2012: 199 [14 December 2021] . ISBN 978-1-4613-2655-7（英语） . ^ Mironov, K. E. A transport reaction for the growth of praseodymium phospide . Journal of Crystal Growth. 1 January 1968, 3–4 : 150–152 [14 December 2021] . Bibcode:1968JCrGr...3..150M doi:10.1016/0022-0248(68)90115-2 （英语） . ^ Nowacki, J. D. H. Donnay, and Werner. Crystal Data: Classification of Substances by Space Groups and their Identification from Cell Dimensions . Geological Society of America . 1954: 509 [14 December 2021] . ISBN 978-0-8137-1060-0（英语） . ^ Yaduvanshi, Namrata; Singh, Sadhna. Exploration of pressure induced phase transition in praseodymium phosphide (PrP) with the NaCl-type structure . Dae Solid State Physics Symposium 2017. AIP Conference Proceedings 1942 (1): 030001. 10 April 2018 [14 December 2021] . Bibcode:2018AIPC.1942c0001Y doi:10.1063/1.5028582 原始内容 存档于2021-12-14）.
