苯甲酰溴

苯甲酰溴
识别
CAS号	618-32-6
性质
化学式	C6H5C(O)Br
摩尔质量	185.02 g·mol⁻¹
熔点	−24 °C（249 K）
沸点	218.5 °C（491.6 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

苯甲酰溴是一种有机化合物，化学式为C₇H₅BrO，它是苯甲酸的酰溴衍生物。它可由苯甲醛和二溴三聚氰酸在二氯甲烷中反应制得。^[2]苯甲醛和溴化亚砜^[3]或N-溴代丁二酰亚胺^[4]的反应，以及苯甲酰氟和三溴化硼的反应^[5]都可制得苯甲酰溴。它和苯硫酚亚铊反应，可以得到硫代苯甲酸-S-苯酯；硒代底物的反应类似。^[6]在乙酸钯催化下，它和苯基环氧乙烷反应，可以得到苯甲酸-β-溴苯乙酯。^[7]

参考文献[编辑]

^ ^1.0 ^1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-09-21].
^ Young-Do Kwon, Minh Thanh La, Hee-Kwon Kim. Aerobic oxidative esterification and thioesterification of aldehydes using dibromoisocyanuric acid under mild conditions: no metal catalysts required. New Journal of Chemistry. 2018, 42 (13): 10833–10841 [2021-09-21]. ISSN 1144-0546. doi:10.1039/C8NJ01085D （英语）.
^ S. D. Saraf. Reaction of Thionyl Bromide with Aromatic Aldehydes. Journal für Praktische Chemie. 1981, 323 (4): 673–676 [2021-09-21]. ISSN 0021-8383. doi:10.1002/prac.19813230421. （原始内容存档于2021-09-21）（德语）.
^ Yak-Fa Cheung. N-bromosuccinimide: direct oxidation of aldehydes to acid bromides. Tetrahedron Letters. 1979-01, 20 (40): 3809–3810 [2021-09-21]. doi:10.1016/S0040-4039(01)95530-3. （原始内容存档于2018-06-10）（英语）.
^ Yagupol'skii, L. M.; Kondratenko, N. V. Exchange of halogen atoms in trihalomethyl groups. Zhurnal Obshchei Khimii, 1967. 37 (8): 1770-1775. ISSN 0044-460X.
^ Michael R. Detty, Gary P. Wood. Substitution reactions of thallous thiophenoxide and thallous phenyl selenide with halogen-bearing substrates. The Journal of Organic Chemistry. 1980-01, 45 (1): 80–89 [2021-09-21]. ISSN 0022-3263. doi:10.1021/jo01289a018 （英语）.
^ Jean Fotie, Brandy R. Adolph, Shreya V. Bhatt, Casey C. Grimm. Palladium(II) acetate catalyzed acylative cleavage of cyclic and acyclic ethers under neat conditions. Tetrahedron Letters. 2017-12, 58 (49): 4648–4651 [2021-09-21]. doi:10.1016/j.tetlet.2017.10.080. （原始内容存档于2018-07-01）（英语）.

[SRC-1] 1.0 ^1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-09-21].

[2] Young-Do Kwon, Minh Thanh La, Hee-Kwon Kim. Aerobic oxidative esterification and thioesterification of aldehydes using dibromoisocyanuric acid under mild conditions: no metal catalysts required. New Journal of Chemistry. 2018, 42 (13): 10833–10841 [2021-09-21]. ISSN 1144-0546. doi:10.1039/C8NJ01085D （英语）.

[3] S. D. Saraf. Reaction of Thionyl Bromide with Aromatic Aldehydes. Journal für Praktische Chemie. 1981, 323 (4): 673–676 [2021-09-21]. ISSN 0021-8383. doi:10.1002/prac.19813230421. （原始内容存档于2021-09-21）（德语）.

[4] Yak-Fa Cheung. N-bromosuccinimide: direct oxidation of aldehydes to acid bromides. Tetrahedron Letters. 1979-01, 20 (40): 3809–3810 [2021-09-21]. doi:10.1016/S0040-4039(01)95530-3. （原始内容存档于2018-06-10）（英语）.

[5] Yagupol'skii, L. M.; Kondratenko, N. V. Exchange of halogen atoms in trihalomethyl groups. Zhurnal Obshchei Khimii, 1967. 37 (8): 1770-1775. ISSN 0044-460X.

[6] Michael R. Detty, Gary P. Wood. Substitution reactions of thallous thiophenoxide and thallous phenyl selenide with halogen-bearing substrates. The Journal of Organic Chemistry. 1980-01, 45 (1): 80–89 [2021-09-21]. ISSN 0022-3263. doi:10.1021/jo01289a018 （英语）.

[7] Jean Fotie, Brandy R. Adolph, Shreya V. Bhatt, Casey C. Grimm. Palladium(II) acetate catalyzed acylative cleavage of cyclic and acyclic ethers under neat conditions. Tetrahedron Letters. 2017-12, 58 (49): 4648–4651 [2021-09-21]. doi:10.1016/j.tetlet.2017.10.080. （原始内容存档于2018-07-01）（英语）.

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