1,3,5-三碘苯

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1,3,5-三碘苯
识别
CAS号 626-44-8  ✓
性质
化学式 C6H3I3
摩尔质量 455.8 g·mol−1
熔点 183 °C(456 K)[1]
若非注明,所有数据均出自一般条件(25 ℃,100 kPa)下。

1,3,5-三碘苯是一种有机化合物,化学式为C6H3I3,它是三碘苯同分异构体之一。它可由1,3,5-三(三甲基硅基)苯和一氯化碘反应制得[2],或通过2,4,6-三碘苯胺重氮化脱氨基得到[3]。它和2-氨基苯硼酸偶联,可以得到1,3,5-(2-氨基苯基)苯。[4]

参考文献[编辑]

  1. ^ Beinhoff, Matthias; Karakaya, Birol; Schluter, A. Dieter. Synthesis of low generation phenylenealkylene dendrons as nonpolar building blocks for a dendrimer construction set. Synthesis, 2003. 1. 79-90.
  2. ^ Motonori Banno, Tomoko Yamaguchi, Kanji Nagai, Christian Kaiser, Stefan Hecht, Eiji Yashima. Optically Active, Amphiphilic Poly( meta -phenylene ethynylene)s: Synthesis, Hydrogen-Bonding Enforced Helix Stability, and Direct AFM Observation of Their Helical Structures. Journal of the American Chemical Society. 2012-05-23, 134 (20): 8718–8728 [2021-11-25]. ISSN 0002-7863. doi:10.1021/ja303204m (英语). 
  3. ^ S. Z. Vatsadze, I. D. Titanyuk, A. V. Chernikov, N. V. Zyk. Synthesis of diiodo- and triiodoanilines by iodination of aniline with potassium dichloroiodate and preparation of 1,3,5-triiodobenzene. Russian Chemical Bulletin. 2004-02, 53 (2): 471–473 [2021-11-25]. ISSN 1066-5285. doi:10.1023/B:RUCB.0000030826.76441.af (英语). 
  4. ^ Piotr Piątek, Norbert Słomiany. 1,3,5-Tris(2′-aminophenyl)benzene: A Novel Platform for Molecular Receptors. Synlett. 2006-08, 2006 (13): 2027–2030 [2021-11-25]. ISSN 0936-5214. doi:10.1055/s-2006-948199 (英语).