1,4-二碘苯

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1,4-二碘苯
别名 对二碘苯
识别
CAS号 624-38-4  ✓
性质
化学式 C6H4I2
摩尔质量 329.9 g·mol−1
熔点 130-131 °C(403-404 K)[1]
沸点 268-269 °C(541-542 K)(分解)[2]
若非注明,所有数据均出自一般条件(25 ℃,100 kPa)下。

1,4-二碘苯是一种有机化合物,化学式为C6H4I2。它可由碘苯四氧化三铅三氟乙酸中反应制得,副产物为1,2-二碘苯(12%)。[3]它也可通过重氮氟硼酸盐的反应制得。[4]在催化下,它和苯硼酸反应,可以得到对三联苯[5]

参考文献[编辑]

  1. ^ N. N. Vlasova, L. I. Belousova, A. V. Vlasov, T. I. Vakul’skaya, S. S. Khutsishvili, M. G. Voronkov. Photochemical reactions of acyl iodides with haloarenes. Doklady Chemistry. 2011-06, 438 (2): 164–166 [2021-11-25]. ISSN 0012-5008. doi:10.1134/S0012500811060048 (英语). 
  2. ^ Sung-Youn Chang, Hye-Young Jang, Kyu-Sung Jeong. Self-Assembled Metallocycles with Two Interactive Binding Domains. Chemistry - A European Journal. 2004-09-06, 10 (17): 4358–4366 [2021-11-25]. ISSN 0947-6539. doi:10.1002/chem.200400227 (英语). 
  3. ^ Makhon'kov, D. I.; Cheprakov, A. V.; Rodkin, M. A.; Serguchev, Yu. A.; Davydova, V. G.; Beletskaya, I. P. Oxidative halogenation of aromatic compounds in the Pb3O4-​halide-​CF3COOH system. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1987. 11: 2609-2611. ISSN 0002-3353.
  4. ^ Somnath S. Gholap. An Efficient Gram Scale Synthesis of Aryl Iodides from Aryl Diazofluoroborates in Water under Mild Conditions. Letters in Organic Chemistry. 2018-06-13, 15 (7): 594–599 [2021-11-25]. doi:10.2174/1570178614666170907120329 (英语). 
  5. ^ Mehul B. Thathagar,, Jurriaan Beckers, and, Gadi Rothenberg*. Copper-Catalyzed Suzuki Cross-Coupling Using Mixed Nanocluster Catalysts. ACS Publications. 2002-09-12 [2021-11-25]. doi:10.1021/ja027716 (英语).