2,3-二甲基-2-丁醇

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2,3-二甲基-2-丁醇
英文名 2,3-Dimethyl-2-butanol
识别
CAS号 594-60-5  ✓
性质
化学式 C6H14O
摩尔质量 102.17 g·mol−1
密度 0.8294 g·cm−3(20 °C)[1]
0.8155 g·cm−3(25 °C)[2]
熔点 −11.3 °C(261.8 K)[3]
−14 °C(259 K)[4]
沸点 118.4 °C(391.5 K)[4]
118.6 °C(391.8 K)[5]
溶解性 2.3 g(25 °C)[6]
pKa 15.24±0.29[6]
若非注明,所有数据均出自一般条件(25 ℃,100 kPa)下。

2,3-二甲基-2-丁醇是一种有机化合物,化学式为C6H14O六碳醇的同分异构体之一。它可由2,3-二甲基-2-丁烯硼氢化-氧化反应制得。[7]甲基(三氟甲基)过氧化酮对2,3-二甲基丁烷的氧化也能得到该产物。[8]它和金属的二(三甲基硅基)氨基化物反应,生成金属的醇盐。[9]

参考文献[编辑]

  1. ^ Levina, R. Ya.; Tantsyreva, T. I.; Fainzil'berg, A. A. Synthesis of hydrocarbons. XX. Synthesis of alkenes and alkanes with a quaternary carbon atom. Zhurnal Obshchei Khimii, 1952. 22: 571-577. ISSN: 0044-460X.
  2. ^ C. G. Overberger, M. B. Berenbaum. Azo Nitriles. VII. 1 Decomposition Products from 2,2'-Azo-bis-2,3,3-trimethylbutyronitrile. Products Obtained from a Substituted Neopentyl Radical. Journal of the American Chemical Society. 1952-07, 74 (13): 3293–3295 [2019-11-08]. ISSN 0002-7863. doi:10.1021/ja01133a022 (英语). 
  3. ^ M. GaŁązka, E. Juszyńska, P.M. Zieliński. General specific heat dependences on temperature in neohexanol and its isomers. Physica B: Condensed Matter. 2011-12, 406 (23): 4342–4349 [2019-11-08]. doi:10.1016/j.physb.2011.08.065 (英语). 
  4. ^ 4.0 4.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2019-11-8]
  5. ^ Mohammad Goodarzi, Matheus P. Freitas. Predicting Boiling Points of Aliphatic Alcohols through Multivariate Image Analysis Applied to Quantitative Structure−Property Relationships. The Journal of Physical Chemistry A. 2008-11-06, 112 (44): 11263–11265 [2019-11-08]. ISSN 1089-5639. doi:10.1021/jp8059085 (英语). 
  6. ^ 6.0 6.1 Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-11-8]
  7. ^ Herbert C. Brown, M. Mark Midland, George W. Kabalka. Organoboranes for synthesis. 5. Tetrahedron. 1986-01, 42 (20): 5523–5530 [2019-11-08]. doi:10.1016/S0040-4020(01)88155-2 (英语). 
  8. ^ Jack K. Crandall, Ruggero Curci, Lucia D'Accolti, Caterina Fusco. Methyl(trifluoro-methyl)dioxirane. John Wiley & Sons, Ltd. 2005-10-15 [2019-11-08]. ISBN 9780471936237. doi:10.1002/047084289x.rm267.pub2 (英语). 
  9. ^ Timo Hatanpää, Kaupo Kukli, Mikko Ritala, Markku Leskelä. Crystal structures and thermal properties of some rare earth alkoxides with tertiary alcohols: Possible precursors for atomic layer deposition of rare earth oxides. Journal of Thermal Analysis and Calorimetry. 2011-07, 105 (1): 61–71 [2019-11-08]. ISSN 1388-6150. doi:10.1007/s10973-011-1546-1 (英语).