4-溴吡啶

编辑链接
维基百科，自由的百科全书
4-溴吡啶
识别
CAS号 1120-87-2  checkY
性质
化学式 C5H4BrN
摩尔质量 158 g·mol−1
熔点 6 °C[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

4-溴吡啶是一种有机化合物，化学式为C5H4BrN。它可由4-氨基吡啶的重氮化反应制得。[2]它和2-溴吡啶（锂化后处理为有机锌试剂）在钯配合物的催化锌进行根岸偶联反应，可以制得2,4'-联吡啶。[3]

参考文献[编辑]

  1. ^ Cumper, Charles W. N.; Vogel, Arthur I. 920. Physical properties and chemical constitution. Part XXX. The dipole moments of some halogeno- and cyano-pyridines. Journal of the Chemical Society (Resumed). 1960: 4723. ISSN 0368-1769. doi:10.1039/jr9600004723. 
  2. ^ Murray, Arthur; Langham, Wright H. A Synthesis of Isonicotinic Acid by Halogen—Metal Exchange and Its Application to the Preparation of Isonicotinic-C14Acid Hydrazide1. Journal of the American Chemical Society. 1952, 74 (24): 6289–6290. ISSN 0002-7863. doi:10.1021/ja01144a515. 
  3. ^ Sidler, Daniel R; Barta, Nancy; Li, Wenjie; Hu, Essa; Matty, Louis; Ikemoto, Nori; Campbell, Jeffrey S; Chartrain, Michel; Gbewonyo, Kozo; Boyd, Russell; Corley, Edward G; Ball, Richard G; Larsen, Robert D; Reider, Paul J. Efficient synthesis of the optically active dihydropyrimidinone of a potent α1A- selective adrenoceptor antagonist. Canadian Journal of Chemistry. 2002, 80 (6): 646–652. ISSN 0008-4042. doi:10.1139/v02-079. 
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