苯戊酮
| 苯戊酮 | |
|---|---|
| |
| |
| 别名 | 1-Phenyl-1-pentanone Valerophenone Butyl phenyl ketone n-Butyl phenyl ketone |
| 识别 | |
| CAS号 | 1009-14-9 
|
| PubChem | 66093 |
| ChemSpider | 59482 |
| SMILES |
|
| InChI |
|
| InChIKey | XKGLSKVNOSHTAD-UHFFFAOYAK |
| ChEBI | 36812 |
| 性质 | |
| 化学式 | C11H14O |
| 摩尔质量 | 162.23 g/mol g·mol⁻¹ |
| 密度 | 0.988 g/cm3 |
| 熔点 | -9.4 °C（264 K） |
| 沸点 | 105 - 107 °C（271 K）（5 mmHg） |
| 危险性 | |
| NFPA 704 |
 1
2
0
|
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
苯戊酮（英语：Valerophenone）是一种烷基芳香酮，化学式为C6H5C(O)C4H9。它是一种无色液体，可溶于有机溶剂。它通常由用戊酰氯将苯酰化制备。[1]
选定的反应[编辑]
苯戊酮具有前手性，会进行对映选择性氢化生成相应的醇。[2]
参见[编辑]
参考文献[编辑]
- ^ Milstein, D.; Stille, J. K. A general, selective, and facile method for ketone synthesis from acid chlorides and organotin compounds catalyzed by palladium. Journal of the American Chemical Society. 1978, 100 (11): 3636–3638. doi:10.1021/ja00479a077.
- ^ Ohkuma, Takeshi; Ooka, Hirohito; Hashiguchi, Shohei; Ikariya, Takao; Noyori, Ryoji. Practical Enantioselective Hydrogenation of Aromatic Ketones. Journal of the American Chemical Society. 1995, 117 (9): 2675–2676. doi:10.1021/ja00114a043.
- ^ Klan P.; Janosek J.; Krz Z. Photochemistry of valerophenone in solid solutions. Journal of Photochemistry and Photobiology A: Chemistry. 2000, 134 (1): 37–44. doi:10.1016/S1010-6030(00)00244-6.
- ^ R. G. Zepp; M. M. Gumz; W. L. Miller & H. Gao. Photoreaction of Valerophenone in Aqueous Solution. J. Phys. Chem. A. 1998, 102 (28): 5716–5723. Bibcode:1998JPCA..102.5716Z. doi:10.1021/jp981130l.
- ^ Imamura Y, Narumi R, Shimada H. Inhibition of carbonyl reductase activity in pig heart by alkyl phenyl ketones (PDF). J Enzyme Inhib Med Chem. 2007, 22 (1): 105–9 [2022-08-06]. PMID 17373555. S2CID 30284545. doi:10.1080/14756360600954023. （原始内容存档 (PDF)于2019-09-05）.