二氯丙二腈

二氯丙二腈
别名	二氰基二氯甲烷
识别
CAS号	13063-43-9
性质
化学式	C3Cl2N2
摩尔质量	134.95 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

二氯丙二腈是一种有机化合物，化学式为C₃Cl₂N₂。它可由丙二腈和氯气在水中反应制得。^[1]它在氯化亚铜/dppf催化下可以和烯烃发生加成反应，如和4-苯基-1-丁烯反应，得到2-氯-2-(2-氯-4-苯基丁基)丙二腈。^[2]在苄基三乙基氯化铵存在下，它和二氯化硫反应，可以得到3,4,4,5-四氯-4H-1,2,6-硫杂二嗪。^[3]

参考文献[编辑]

^ Carpenter, Wayne R.; Armstrong, Patricia. N-1,1-Trichlorocyanoacetimidoyl Chloride. The Journal of Organic Chemistry (American Chemical Society (ACS)). 1964, 29 (9): 2772–2773. ISSN 0022-3263. doi:10.1021/jo01032a510.
^ Kamijo, Shin; Yokosaka, Shinya; Inoue, Masayuki. Attachment of carbonyl functionalities onto olefins via copper-promoted radical reaction of dichloromethylcyanides. Tetrahedron (Elsevier BV). 2012, 68 (26): 5290–5296. ISSN 0040-4020. doi:10.1016/j.tet.2012.01.089.
^ Kalogirou, Andreas S.; Koutentis, Panayiotis A. Synthesis of 2-(4H-1,2,6-thiadiazin-4-ylidene)malononitriles. Tetrahedron (Elsevier BV). 2014, 70 (44): 8334–8342. ISSN 0040-4020. doi:10.1016/j.tet.2014.09.008.

[1] Carpenter, Wayne R.; Armstrong, Patricia. N-1,1-Trichlorocyanoacetimidoyl Chloride. The Journal of Organic Chemistry (American Chemical Society (ACS)). 1964, 29 (9): 2772–2773. ISSN 0022-3263. doi:10.1021/jo01032a510.

[2] Kamijo, Shin; Yokosaka, Shinya; Inoue, Masayuki. Attachment of carbonyl functionalities onto olefins via copper-promoted radical reaction of dichloromethylcyanides. Tetrahedron (Elsevier BV). 2012, 68 (26): 5290–5296. ISSN 0040-4020. doi:10.1016/j.tet.2012.01.089.

[3] Kalogirou, Andreas S.; Koutentis, Panayiotis A. Synthesis of 2-(4H-1,2,6-thiadiazin-4-ylidene)malononitriles. Tetrahedron (Elsevier BV). 2014, 70 (44): 8334–8342. ISSN 0040-4020. doi:10.1016/j.tet.2014.09.008.

[1]

[2]

[3]