六氟铟酸铵

六氟铟酸铵
别名	六氟合铟(III)酸铵
识别
CAS号	15273-84-4
性质
化学式	(NH4)3InF6
摩尔质量	282.92 g·mol⁻¹
外观	无色晶体
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

六氟铟酸铵是一种无机化合物，化学式为(NH₄)₃InF₆。它可由氟化铵和溴化铟在无水甲醇中反应得到，^[2]或氟化铵和氟化铟在水溶液中反应沉淀得到。^[3]它在120~170 °C分解，得到NH₄InF₄，在185~300 °C分解为InF₃。而NH₄InF₄吸收氨后形成的NH₄InF₄·NH₃的热分解经过InF₃·NH₃等中间体得到InN。^[4]

参考文献[编辑]

^ John E. Roberts, A. W. Laubengayer. Fluoride Complexes of Indium(III) 1. Journal of the American Chemical Society. 1957-11, 79 (22): 5895–5897 [2022-05-25]. ISSN 0002-7863. doi:10.1021/ja01579a016. （原始内容存档于2022-05-25）（英语）.
^ Helmut M. Haendler, Frederic A. Johnson, David S. Crocket. The Synthesis of Ammonium Fluorometallates in Methanol 1a. Journal of the American Chemical Society. 1958-06, 80 (11): 2662–2664 [2022-05-25]. ISSN 0002-7863. doi:10.1021/ja01544a017. （原始内容存档于2022-05-25）（英语）.
^ Zakalyukin, R. M.; Boltalin, A. I.; Fedorov, P. P. Synthesis of ammonium hexafluoroindate. Zhurnal Neorganicheskoi Khimii, 2001. 46 (8): 1247-1249. ISSN 0044-457X.
^ Mermant, Guy; Belinski, Colette; Lalau-Keraly, Francois. Thermal decomposition of ammonium indium hexafluoride in an inert atmosphere and of ammonium indium tetrafluoride in the presence of ammonia. Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1967. 265 (25): 1447-1450. ISSN 0567-6541.

[1] John E. Roberts, A. W. Laubengayer. Fluoride Complexes of Indium(III) 1. Journal of the American Chemical Society. 1957-11, 79 (22): 5895–5897 [2022-05-25]. ISSN 0002-7863. doi:10.1021/ja01579a016. （原始内容存档于2022-05-25）（英语）.

[2] Helmut M. Haendler, Frederic A. Johnson, David S. Crocket. The Synthesis of Ammonium Fluorometallates in Methanol 1a. Journal of the American Chemical Society. 1958-06, 80 (11): 2662–2664 [2022-05-25]. ISSN 0002-7863. doi:10.1021/ja01544a017. （原始内容存档于2022-05-25）（英语）.

[3] Zakalyukin, R. M.; Boltalin, A. I.; Fedorov, P. P. Synthesis of ammonium hexafluoroindate. Zhurnal Neorganicheskoi Khimii, 2001. 46 (8): 1247-1249. ISSN 0044-457X.

[4] Mermant, Guy; Belinski, Colette; Lalau-Keraly, Francois. Thermal decomposition of ammonium indium hexafluoride in an inert atmosphere and of ammonium indium tetrafluoride in the presence of ammonia. Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1967. 265 (25): 1447-1450. ISSN 0567-6541.

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