2,5-双脱氧-SZ-685C

2,5-双脱氧-SZ-685C
	IUPAC名; (3S)-1,3,8-Trihydroxy-6-methoxy-3-methyl-2,4-dihydro-1H-anthracene-9,10-dione
识别
CAS号	97400-70-9
PubChem	5459129
ChemSpider	9510649
SMILES	C[C@]1(CC(C2=C(C1)C(=O)C3=CC(=CC(=C3C2=O)O)OC)O)O;
InChI	1/C16H16O6/c1-16(21)5-9-13(11(18)6-16)15(20)12-8(14(9)19)3-7(22-2)4-10(12)17/h3-4,11,17-18,21H,5-6H2,1-2H3/t11-,16-/m0/s1;
InChIKey	LRHFZXBVDMVFCW-ZBEGNZNMBC
性质
化学式	C16H16O6
摩尔质量	304.29 g·mol−1
外观	橙黄色针状晶体
熔点	162-164 °C（1S,3R）; 183-185 °C（1S,3S）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

2,5-双脱氧-SZ-685C（英语：Austrocortilutein）（1,2,3,4-四氢-1,3,8-三羟基-6-甲氧基-3-甲基-9,10-蒽醌）是一种有机化合物，化学式为C₁₆H₁₆O₆，其英文名“austrocortirubin”源自于澳大利亚的丝膜菌属（Cortinarius）的毒蕈。^[2]它可以用于制备3-脱氧交替酚A。^[3]

参考文献[编辑]

^ ^1.0 ^1.1 Melvyn Gill, Albin F. Smrdel, Richard J. Strauch and Michael J. Begley. Pigments of fungi. Part 12. Structure and absolute stereochemistry of antibiotic tetrahydroanthraquinones from the fungus Dermocybe splendida Horak. X-Ray structure determination of austrocortirubin phenylboronate and austrocortilutein acetonide. J. Chem. Soc., Perkin Trans. 1, 1990, 1583-1592. doi:10.1039/P19900001583.
^ Melvyn Gill; Richard J. Strauch (1985). New tetrahydroanthraquinones from the genus Cortinarius. Tetrahedron Letters, 26 (21), 2593–2596. doi:10.1016/s0040-4039(00)98845-2.
^ Burns, CJ; Gill, M; Gimenez, A (1991). Pigments of Fungi. XXIV. New Trihydroxylated Tetrahydroanthraquinones From an Australian Fungus Belonging to the Genus Dermocybe. Australian Journal of Chemistry, 44 (12), 1729–1736. doi:10.1071/ch9911729.

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[Gill-1] 1.0 ^1.1 Melvyn Gill, Albin F. Smrdel, Richard J. Strauch and Michael J. Begley. Pigments of fungi. Part 12. Structure and absolute stereochemistry of antibiotic tetrahydroanthraquinones from the fungus Dermocybe splendida Horak. X-Ray structure determination of austrocortirubin phenylboronate and austrocortilutein acetonide. J. Chem. Soc., Perkin Trans. 1, 1990, 1583-1592. doi:10.1039/P19900001583.

[2] Melvyn Gill; Richard J. Strauch (1985). New tetrahydroanthraquinones from the genus Cortinarius. Tetrahedron Letters, 26 (21), 2593–2596. doi:10.1016/s0040-4039(00)98845-2.

[3] Burns, CJ; Gill, M; Gimenez, A (1991). Pigments of Fungi. XXIV. New Trihydroxylated Tetrahydroanthraquinones From an Australian Fungus Belonging to the Genus Dermocybe. Australian Journal of Chemistry, 44 (12), 1729–1736. doi:10.1071/ch9911729.

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