三(4-甲苯基)均三嗪

三(4-甲苯基)均三嗪
识别
CAS号	6726-45-0
SMILES	N=1C(=NC(=NC1C=2C=CC(=CC2)C)C=3C=CC(=CC3)C)C=4C=CC(=CC4)C;
性质
化学式	C24H21N3
摩尔质量	351.44 g·mol−1
外观	白色针状晶体
熔点	284—286 °C（557—559 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

三(4-甲苯基)均三嗪是一种有机化合物，化学式为C₂₄H₂₁N₃。它可由三聚氯氰和干甲苯在三氯化铝催化下于60 °C反应得到；^[1]或由4-甲基苯甲腈在己胺和碘化亚钐催化下三聚得到。^[3]它在硫酸、乙酸及乙酸酐体系中可以被三氧化铬氧化为三(4-羧基苯基)均三嗪。^[1]它和硝硫混酸在80 °C反应，可以得到三(4-甲基-3,5-二硝基苯基)均三嗪。^[4]

参考文献

^ ^1.0 ^1.1 ^1.2 Jihye Park; Dawei Feng; Hong-Cai Zhou. Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores. J. Am. Chem. Soc. 2015, 137, 4, 1663–1672. doi:10.1021/ja5123528.
^ John H. Forsberg; Vincent T. Spaziano; Stephen P. Klump; Kathleen M. Sanders. Lanthanide(III) ion catalyzed reaction of ammonia and nitriles: Synthesis of 2,4,6-trisubstituted-s-triazines. Journal of Heterocyclic Chemistry, 1988. 25 (3): 767-770. doi:10.1002/jhet.5570250312.
^ Daofeng Sun; Shengqian Ma; Yanxiong Ke; Tracy M Peterson; Hong-Cai Zhou. Synthesis, characterization, and photoluminescence of isostructural Mn, Co, and Zn MOFs having a diamondoid structure with large tetrahedral cages and high thermal stability. Chem. Commun., 2005, 2663-2665. doi:10.1039/B502007G.
^ Yu Gong; Shaofeng Huang; Zepeng Lei; Lacey Wayment; Hongxuan Chen; Wei Zhang. Double-Walled Covalent Organic Frameworks with High Stability. Chemistry - A European Journal (2023), 29 (63), e202302135. doi:10.1002/chem.202302135.

[Zhou-1] 1.0 ^1.1 ^1.2 Jihye Park; Dawei Feng; Hong-Cai Zhou. Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores. J. Am. Chem. Soc. 2015, 137, 4, 1663–1672. doi:10.1021/ja5123528.

[2] John H. Forsberg; Vincent T. Spaziano; Stephen P. Klump; Kathleen M. Sanders. Lanthanide(III) ion catalyzed reaction of ammonia and nitriles: Synthesis of 2,4,6-trisubstituted-s-triazines. Journal of Heterocyclic Chemistry, 1988. 25 (3): 767-770. doi:10.1002/jhet.5570250312.

[3] Daofeng Sun; Shengqian Ma; Yanxiong Ke; Tracy M Peterson; Hong-Cai Zhou. Synthesis, characterization, and photoluminescence of isostructural Mn, Co, and Zn MOFs having a diamondoid structure with large tetrahedral cages and high thermal stability. Chem. Commun., 2005, 2663-2665. doi:10.1039/B502007G.

[4] Yu Gong; Shaofeng Huang; Zepeng Lei; Lacey Wayment; Hongxuan Chen; Wei Zhang. Double-Walled Covalent Organic Frameworks with High Stability. Chemistry - A European Journal (2023), 29 (63), e202302135. doi:10.1002/chem.202302135.

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