六苯基二锡
外观
六苯基二锡 | |
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识别 | |
CAS号 | 1064-10-4 ![]() |
性质 | |
化学式 | C36H30Sn2 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
六苯基二锡是一种有机锡化合物,化学式为C36H30Sn2。
合成
[编辑]它也可以由一、二或三苯基氯化锡和金属钠的还原反应得到。[2][3]
异氰酸苯酯和三苯基氢化锡的反应也能得到六苯基二锡。[4]
性质
[编辑]六苯基二锡在280 °C以上分解,[5]在紫外线下不稳定。[2][6]在250 °C以上,它会变黄。它也能和硫反应:
它属于单斜晶系,空间群P21/c。[8]
参考文献
[编辑]- ^ B. J. Aylett, [《六苯基二锡》在Google Books的内容。 Organometallic Compounds Volume One The Main Group Elements Part Two Groups IV and V], Springer Science & Business Media: pp. 267, (德文)
- ^ 2.0 2.1 Rudolf Bock, [《六苯基二锡》在Google Books的内容。 Triphenyltin Compounds and Their Degradation Products], Springer Science & Business Media: pp. 16, (德文)
- ^ Michel Pereyre, Jean-Paul Quintard, Alain Rahm, [《六苯基二锡》在Google Books的内容。 Tin in Organic Synthesis], Butterworth-Heinemann: pp. 335, (德文)
- ^ S. Coffey, [《六苯基二锡》在Google Books的内容。 Monocarbonyl Derivatives of Aliphatic Hydrocarbons, Their Analogues and Derivatives A Modern Comprehensive Treatise], Elsevier: pp. 359, (德文)
- ^ Eintrag zu Hexaphenyldistannan in der GESTIS-Stoffdatenbank des IFA, abgerufen am 9. Januar 2019.
- ^ L. Wilputte-Steinert, J. Nasielski: The photochemistry of aromatic compounds IV. Photochemical behaviour of hexaphenylditin. In: Journal of Organometallic Chemistry. 24, 1970, S. 113, doi:10.1016/S0022-328X(00)91572-9.
- ^ Karin Eckardt, Hartmut Fuess, Masakazu Hattori, Ryuichi Ikeda, Hiroshi Ohki, Alarich Weiss: Structure and Dynamics of Crystal Solvates Hexaphenylditin • 2X, X=Benzene, Toluene, Fluorobenzene, Chlorobenzene, and Aniline. An X-Ray, P(VAPOR)=ƒ(T)> and 2H NMR Study. In: Zeitschrift für Naturforschung A. 50, 1995, doi:10.1515/zna-1995-0808.
- ^ J. Trotter, [《六苯基二锡》在Google Books的内容。 Structure Reports Organic Section], Springer Science & Business Media: pp. 550, (德文)
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