8-氯荧蒽

8-氯荧蒽
识别
CAS号	145730-31-0
SMILES	ClC1=CC=C2C3=CC=CC=4C=CC=C(C2=C1)C43;
性质
化学式	C16H9Cl
摩尔质量	236.7 g·mol−1
外观	黄色固体
熔点	108-110 °C
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

8-氯荧蒽是一种氯代芳烃，化学式为C₁₆H₉Cl。它可由4-氯苯硼酸（维基数据所列：Q69757145）和1,8-二溴萘（维基数据所列：Q72464608）在钯配合物催化下反应制得；^[1]或由8-氨基荧蒽和亚硝酸钠在酸性条件下反应，再氯化得到。^[2]它和双频哪醇二硼在催化下反应，可以得到荧蒽-8-硼酸频哪醇酯。^[3]

参考文献

^ ^1.0 ^1.1 ^1.2 Nahed Ketata, Linhao Liu, Ridha Ben Salem and Henri Doucet. Mono or double Pd-catalyzed C–H bond functionalization for the annulative π-extension of 1,8-dibromonaphthalene: a one pot access to fluoranthene derivatives. Beilstein J. Org. Chem. 2024, 20, 427–435. doi:10.3762/bjoc.20.37.
^ Van Haeringen, C. J.; Lugtenburg, J.; Cornelisse, J. (1996). Synthesis and Characterization of Chloro-, Bromo-, Cyano-, Formyl-, and Methylfluoranthenes. Polycyclic Aromatic Compounds, 8 (1), 9–22. doi:10.1080/10406639608048330.
^ Kim, Minjun; Lee, Dong Hoon; Suh, Sang Duk; Kim, Young Seok; Kim, Donghee; Oh, Joongsuk; Lee, Da Jung. Preparation of triazine-linked dibenzofuran compounds and organic light-emitting devices comprising them. 2023. WO2023003146 A1.

[Nahed-1] 1.0 ^1.1 ^1.2 Nahed Ketata, Linhao Liu, Ridha Ben Salem and Henri Doucet. Mono or double Pd-catalyzed C–H bond functionalization for the annulative π-extension of 1,8-dibromonaphthalene: a one pot access to fluoranthene derivatives. Beilstein J. Org. Chem. 2024, 20, 427–435. doi:10.3762/bjoc.20.37.

[2] Van Haeringen, C. J.; Lugtenburg, J.; Cornelisse, J. (1996). Synthesis and Characterization of Chloro-, Bromo-, Cyano-, Formyl-, and Methylfluoranthenes. Polycyclic Aromatic Compounds, 8 (1), 9–22. doi:10.1080/10406639608048330.

[3] Kim, Minjun; Lee, Dong Hoon; Suh, Sang Duk; Kim, Young Seok; Kim, Donghee; Oh, Joongsuk; Lee, Da Jung. Preparation of triazine-linked dibenzofuran compounds and organic light-emitting devices comprising them. 2023. WO2023003146 A1.

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