PCN-14
外观
PCN-14 | |
---|---|
别名 | Cu-PCN-14 |
识别 | |
CAS号 | 1006599-75-2 |
性质 | |
化学式 | C270H162Cu18O90 |
摩尔质量 | 5989.9 g·mol⁻¹ |
外观 | 绿色晶体(二水二DMF合物)[1] |
结构 | |
晶体结构 | 菱方晶系,R3c(二水二DMF合物)[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
PCN-14是一种金属有机框架材料,由铜(II)和5,5'-(9,10-蒽二基)二(1,3-苯二甲酸)配体(H4adip)连接而成,为二水合物。最初于2008年被制得。[1][2]
制备
[编辑]将硝酸铜2.5水合物、H4adip配体加入至DMF溶剂中,并滴加氟硼酸,在75 °C进行溶剂热反应,可以制得PCN-14。[1]
性质
[编辑]参考文献
[编辑]- ^ 1.0 1.1 1.2 1.3 Shengqian Ma, Daofeng Sun, Jason M. Simmons, Christopher D. Collier, Daqiang Yuan, Hong-Cai Zhou. Metal-Organic Framework from an Anthracene Derivative Containing Nanoscopic Cages Exhibiting High Methane Uptake. Journal of the American Chemical Society. 2008-1, 130 (3): 1012–1016 [2019-05-28]. ISSN 0002-7863. doi:10.1021/ja0771639. (原始内容存档于2020-08-01) (英语).
- ^ 2.0 2.1 Shengqian Ma, Jason M. Simmons, Daofeng Sun, Daqiang Yuan, Hong-Cai Zhou. Porous Metal-Organic Frameworks Based on an Anthracene Derivative: Syntheses, Structure Analysis, and Hydrogen Sorption Studies. Inorganic Chemistry. 2009-06-15, 48 (12): 5263–5268 [2019-05-28]. ISSN 0020-1669. doi:10.1021/ic900217t (英语).
- ^ Tony Pham, Katherine A. Forrest, Brian Space. An unusual H 2 sorption mechanism in PCN-14: insights from molecular simulation. Physical Chemistry Chemical Physics. 2016, 18 (31): 21421–21430 [2019-05-28]. ISSN 1463-9076. doi:10.1039/C6CP02650H (英语).