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2,3-二氯苯甲腈

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2,3-二氯苯甲腈
識別
CAS號 6574-97-6  checkY
性質
化學式 C7H3ClN
摩爾質量 136.56 g·mol−1
外觀 淺黃色針狀晶體[1]
熔點 56—57 °C(329—330 K)[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

2,3-二氯苯甲腈是一種有機化合物,化學式為C7H3ClN,它二氯苯甲腈同分異構體之一。它可由2,3-二氯苯甲醛鹽酸羥胺為原料反應製得,[2]2,3-二氯苯甲酰胺三氯氧磷加熱反應也能得到產物。[3]三氯化銦存在下,它可以被硼氫化鈉四氫呋喃中還原為2,3-二氯苄胺。[4]

參考文獻[編輯]

  1. ^ 1.0 1.1 Rahman, Loay K. A.; Scrowston, Richard M. 7-Substituted benzo[b]thiophenes and 1,2-benzisothiazoles. Part 2. Chloro and nitro derivatives. Journal of the Chemical Society, Perkin Transactions 1 (Royal Society of Chemistry (RSC)). 1984: 385. ISSN 0300-922X. doi:10.1039/p19840000385. 
  2. ^ Hongyan Lin, Ziling Zhou, Xiaopeng Ma, Qingqing Chen, Hongwei Han, Xiaoming Wang, Jinliang Qi, Yonghua Yang. One pot synthesis of aryl nitriles from aromatic aldehydes in a water environment. RSC Advances. 2021, 11 (39): 24232–24237 [2021-12-21]. ISSN 2046-2069. doi:10.1039/D1RA03559B (英語). 
  3. ^ Michael D. Meyer, Robert J. Altenbach, Fatima Z. Basha, William A. Carroll, Stephen Condon, Steven W. Elmore, James F. Kerwin, Kevin B. Sippy, Karin Tietje, Michael D. Wendt, Arthur A. Hancock, Michael E. Brune, Steven A. Buckner, Irene Drizin. Structure−Activity Studies for a Novel Series of Tricyclic Substituted Hexahydrobenz[ e ]isoindole α 1A Adrenoceptor Antagonists as Potential Agents for the Symptomatic Treatment of Benign Prostatic Hyperplasia (BPH). Journal of Medicinal Chemistry. 2000-04-01, 43 (8): 1586–1603 [2021-12-21]. ISSN 0022-2623. doi:10.1021/jm990567u (英語). 
  4. ^ Jaime Z. Saavedra, Angel Resendez, Alexander Rovira, Scott Eagon, Dustin Haddenham, Bakthan Singaram. Reaction of InCl 3 with Various Reducing Agents: InCl 3 –NaBH 4 -Mediated Reduction of Aromatic and Aliphatic Nitriles to Primary Amines. The Journal of Organic Chemistry. 2012-01-06, 77 (1): 221–228 [2021-12-21]. ISSN 0022-3263. doi:10.1021/jo201809a. (原始內容存檔於2021-12-21) (英語).