4,4'-二苯醚二甲酸鋱

4,4'-二苯醚二甲酸鋱
識別
CAS號	1392542-51-6（無水） ; 1392484-00-2（五水）
性質
化學式	C42H24O15Tb2
摩爾質量	1086.48 g·mol−1
外觀	無色晶體
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

4,4'-二苯醚二甲酸鋱是一種鋱的羧酸鹽，化學式為Tb₂(C₁₄H₈O₅)₃，為無色晶體。它的五水合物可由4,4'-二苯醚二甲酸鈉和氯化鋱於160 °C水熱反應得到。^[1]4,4'-二苯醚二甲酸和硝酸鋱在三乙胺的存在下，在水中於140 °C反應，可以得到四水合物；羧酸過量會產生酸式鹽。^[2]它在紫外光激發下發出綠光。^[3]

參考文獻

^ Renata Łyszczek. Hydrothermal synthesis, thermal and luminescent investigations of lanthanide(III) coordination polymers based on the 4,4′-oxybis(benzoate) ligand. Journal of Thermal Analysis and Calorimetry. 2012-06, 108 (3): 1101–1110 [2020-05-12]. ISSN 1388-6150. doi:10.1007/s10973-011-1987-6 （英語）.
^ Gao-Feng Liu, Zheng-Ping Qiao, He-Zhou Wang, Xiao-Ming Chen, Guang Yang. Synthesis, structures and photoluminescence of three terbium(iii) dicarboxylate coordination polymers. New Journal of Chemistry. 2002-06-07, 26 (6): 791–795 [2020-05-12]. doi:10.1039/b109869a.
^ Yun Luo, Yanjun Zheng, Guillaume Calvez, Stéphane Freslon, Kevin Bernot, Carole Daiguebonne, Thierry Roisnel, Olivier Guillou. Synthesis, crystal structure and luminescent properties of new lanthanide-containing coordination polymers involving 4,4′-oxy-bis-benzoate as ligand. CrystEngComm. 2013, 15 (4): 706–720 [2020-05-12]. ISSN 1466-8033. doi:10.1039/C2CE26390D （英語）.

[1] Renata Łyszczek. Hydrothermal synthesis, thermal and luminescent investigations of lanthanide(III) coordination polymers based on the 4,4′-oxybis(benzoate) ligand. Journal of Thermal Analysis and Calorimetry. 2012-06, 108 (3): 1101–1110 [2020-05-12]. ISSN 1388-6150. doi:10.1007/s10973-011-1987-6 （英語）.

[2] Gao-Feng Liu, Zheng-Ping Qiao, He-Zhou Wang, Xiao-Ming Chen, Guang Yang. Synthesis, structures and photoluminescence of three terbium(iii) dicarboxylate coordination polymers. New Journal of Chemistry. 2002-06-07, 26 (6): 791–795 [2020-05-12]. doi:10.1039/b109869a.

[3] Yun Luo, Yanjun Zheng, Guillaume Calvez, Stéphane Freslon, Kevin Bernot, Carole Daiguebonne, Thierry Roisnel, Olivier Guillou. Synthesis, crystal structure and luminescent properties of new lanthanide-containing coordination polymers involving 4,4′-oxy-bis-benzoate as ligand. CrystEngComm. 2013, 15 (4): 706–720 [2020-05-12]. ISSN 1466-8033. doi:10.1039/C2CE26390D （英語）.

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