4-碘苯胺

4-碘苯胺
識別
CAS號	540-37-4
SMILES	Ic1ccc(N)cc1;
性質
化學式	C6H6IN
摩爾質量	219.02 g·mol−1
熔點	66 °C（339 K）
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

4-碘苯胺是一種有機化合物，化學式為C₆H₆IN，它是三種碘苯胺的同分異構體之一。它可由4-硝基碘苯被氫氣、硼氫化鈉等還原劑還原得到。^[2]^[3]它和苯甲醛在乙醇中反應，可以得到N-亞苄基-4-碘苯胺。^[4]在鈀催化下、碳酸鉀存在下，它和苯硼酸發生偶聯反應，可以得到4-氨基聯苯。^[5]

參考文獻

^ Shoji Kajigaeshi, Takaaki Kakinami, Hiromichi Yamasaki, Shizuo Fujisaki, Tsuyoshi Okamoto. Halogenation Using Quaternary Ammonium Polyhalides. VII. Iodination of Aromatic Amines by Use of Benzyltrimethylammonium Dichloroiodate(1—). Bulletin of the Chemical Society of Japan. 1988-02, 61 (2): 600–602 [2021-11-15]. ISSN 0009-2673. doi:10.1246/bcsj.61.600. （原始內容存檔於2021-11-15）（英語）.
^ Wenjun Yu, Lan-Lan Lou, Shanshan Li, Tianyuan Ma, Lezi Ouyang, Li Feng, Shuangxi Liu. Highly efficient and durable platinum nanocatalysts stabilized by thiol-terminated poly(N-isopropyl acrylomide) for selective hydrogenation of halonitrobenzene to haloaniline. RSC Advances. 2017, 7 (2): 751–757 [2021-11-15]. ISSN 2046-2069. doi:10.1039/C6RA24773C （英語）.
^ Sanya Pachisia, Ram Kishan, Samanta Yadav, Rajeev Gupta. Half-Sandwich Ruthenium Complexes of Amide-Phosphine Based Ligands: H-Bonding Cavity Assisted Binding and Reduction of Nitro-substrates. Inorganic Chemistry. 2021-02-01, 60 (3): 2009–2022 [2021-11-15]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.0c03505. （原始內容存檔於2021-11-01）（英語）.
^ Romero, Eugenie; Oueslati, Saoussen; Benchekroun, Mohamed; D'Hollander, Agathe C. A.; Ventre, Sandrine; Vijayakumar, Kamsana; Minard, Corinne; Exilie, Cynthia; Tlili, Linda; Retailleau, Pascal; Zavala, Agustin; Elisee, Eddy; Selwa, Edithe; Nguyen, Laetitia A.; Pruvost, Alain; Naas, Thierry; Iorga, Bogdan I.; Dodd, Robert H.; Cariou, Kevin. Azetidinimines as a novel series of non-covalent broad-spectrum inhibitors of β-lactamases with submicromolar activities against carbapenemases of classes A, B and D. ChemRxiv, 2020. 1-31.
^ Hongxue Xie, Huihui Liu, Meimei Wang, Hui Pan, Caixia Gao. L‐Tyrosine‐Pd complex supported on Fe 3 O 4 magnetic nanoparticles: A new catalyst for C–C coupling and Synthesis of sulfides. Applied Organometallic Chemistry. 2020-01, 34 (1) [2021-11-15]. ISSN 0268-2605. doi:10.1002/aoc.5256. （原始內容存檔於2021-11-15）（英語）.

[1] Shoji Kajigaeshi, Takaaki Kakinami, Hiromichi Yamasaki, Shizuo Fujisaki, Tsuyoshi Okamoto. Halogenation Using Quaternary Ammonium Polyhalides. VII. Iodination of Aromatic Amines by Use of Benzyltrimethylammonium Dichloroiodate(1—). Bulletin of the Chemical Society of Japan. 1988-02, 61 (2): 600–602 [2021-11-15]. ISSN 0009-2673. doi:10.1246/bcsj.61.600. （原始內容存檔於2021-11-15）（英語）.

[2] Wenjun Yu, Lan-Lan Lou, Shanshan Li, Tianyuan Ma, Lezi Ouyang, Li Feng, Shuangxi Liu. Highly efficient and durable platinum nanocatalysts stabilized by thiol-terminated poly(N-isopropyl acrylomide) for selective hydrogenation of halonitrobenzene to haloaniline. RSC Advances. 2017, 7 (2): 751–757 [2021-11-15]. ISSN 2046-2069. doi:10.1039/C6RA24773C （英語）.

[3] Sanya Pachisia, Ram Kishan, Samanta Yadav, Rajeev Gupta. Half-Sandwich Ruthenium Complexes of Amide-Phosphine Based Ligands: H-Bonding Cavity Assisted Binding and Reduction of Nitro-substrates. Inorganic Chemistry. 2021-02-01, 60 (3): 2009–2022 [2021-11-15]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.0c03505. （原始內容存檔於2021-11-01）（英語）.

[4] Romero, Eugenie; Oueslati, Saoussen; Benchekroun, Mohamed; D'Hollander, Agathe C. A.; Ventre, Sandrine; Vijayakumar, Kamsana; Minard, Corinne; Exilie, Cynthia; Tlili, Linda; Retailleau, Pascal; Zavala, Agustin; Elisee, Eddy; Selwa, Edithe; Nguyen, Laetitia A.; Pruvost, Alain; Naas, Thierry; Iorga, Bogdan I.; Dodd, Robert H.; Cariou, Kevin. Azetidinimines as a novel series of non-covalent broad-spectrum inhibitors of β-lactamases with submicromolar activities against carbapenemases of classes A, B and D. ChemRxiv, 2020. 1-31.

[5] Hongxue Xie, Huihui Liu, Meimei Wang, Hui Pan, Caixia Gao. L‐Tyrosine‐Pd complex supported on Fe 3 O 4 magnetic nanoparticles: A new catalyst for C–C coupling and Synthesis of sulfides. Applied Organometallic Chemistry. 2020-01, 34 (1) [2021-11-15]. ISSN 0268-2605. doi:10.1002/aoc.5256. （原始內容存檔於2021-11-15）（英語）.

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