二氯化二(2,6-二均三甲苯基苯基)二錫
外觀
二氯化二(2,6-二均三甲苯基苯基)二錫 | |
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識別 | |
CAS號 | 188685-32-7 ![]() |
SMILES |
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性質 | |
化學式 | C48H50Cl2Sn2 |
摩爾質量 | 935.24 g·mol−1 |
外觀 | 黃色晶體[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
二氯化二(2,6-二均三甲苯基苯基)二錫是一種有機化合物,化學式為C48H50Cl2Sn2,或寫作[Sn(Cl)(C6H3Mes2)]2,其中Mes表示2,4,6-三甲苯基。它可由2,6-二均三甲苯基苯基鋰在甲苯中和氯化亞錫反應製得。[1]它和金屬鉀在四氫呋喃中反應,可以得到紫色的Sn8(C6H3Mes2)4。[2]它和Cp*(IPr)Co反應,可以得到深紫色的Sn4(C6H3Mes2)4。[3]
參考文獻
[編輯]- ^ 1.0 1.1 Simons, Richard S.; Pu, Lihung; Olmstead, Marilyn M.; Power, Philip P. Synthesis and Characterization of the Monomeric Diaryls M{C6H3-2,6-Mes2}2 (M = Ge, Sn, or Pb; Mes = 2,4,6-Me3C6H2-) and Dimeric Aryl-Metal Chlorides [M(Cl){C6H3-2,6-Mes2}]2 (M = Ge or Sn). Organometallics (1997), 16(9), 1920-1925. doi:10.1021/om960929l.
- ^ Eichler, Barrett E.; Power, Philip P. Synthesis and characterization of [Sn8(2,6-Mes2C6H3)4] (Mes = 2,4,6-Me3C6H2): a Main group metal cluster with a unique structure. Angewandte Chemie, International Edition (2001), 40(4), 796-797. doi:10.1002/1521-3773(20010216)40:4<796::AID-ANIE7960>3.0.CO;2-5
- ^ Rex C. Handford, T. Alex Wheeler, Prof. T. Don Tilley. Structure and Bonding in a Diamond-Shaped Tin Cluster Possessing a cyclo-Sn4 Core. Chemistry - A European Journal (2020), 26 (28), 6126-6129. doi:10.1002/chem.202000969. Note: Cp* = η5-C5Me5, IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene.