五唑化銀

五唑化銀
識別
CAS號	2408152-17-8
SMILES	[Ag+].N=1N=N[N-]N1;
性質
化學式	AgN5
摩爾質量	177.9 g·mol−1
外觀	蒼白色固體
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

五唑化銀是一種無機化合物，化學式為AgN₅，它可由五唑化鎂或五唑化鈷和硝酸銀反應製得。^[1]^[2]由於它對光照敏感，其晶體結構未能測得。計算表明它的空間群可能為P2₁/c。^[3]

反應[編輯]

五唑化銀和氨水反應，可以得到對空氣穩定的[Ag(NH₃)₂][Ag₃(N₅)₄]。^[1]它和四甲基碘化銨反應，可以得到四甲基五唑化銨；^[4]和三氯化六氨合鈷(III)反應，可以得到三(五唑)化六氨合鈷(III)。^[5]

（左圖）五唑化銀和氨水反應得到的[Ag(NH₃)₂][Ag₃(N₅)₄]晶體；（右圖）以及它的三維框架拓撲結構。^[1]

參考文獻[編輯]

^ ^1.0 ^1.1 ^1.2 ^1.3 Sun, Chengguo; Zhang, Chong; Jiang, Chao; Yang, Chen; Du, Yang; Zhao, Yue; Hu, Bingcheng; Zheng, Zhansheng; Christe, Karl O. Synthesis of AgN5 and its extended 3D energetic framework. Nature Communications (Springer Science and Business Media LLC). 2018-03-28, 9 (1). ISSN 2041-1723. doi:10.1038/s41467-018-03678-y.
^ Wang, Xieyang; Dong, Zhen; Yang, Rui; Zhou, Shengren; Ye, Zhiwen. Syntheses and Characterization of two cyclo‐pentazolate salts. Zeitschrift für anorganische und allgemeine Chemie (Wiley). 2021-01-27, 647 (6): 681–685. ISSN 0044-2313. doi:10.1002/zaac.202000309.
^ Williams, Ashley S.; Nguyen Cong, Kien; Gonzalez, Joseph M.; Oleynik, Ivan I. Crystal structure of silver pentazolates AgN₅ and AgN₆. Dalton Transactions (Royal Society of Chemistry (RSC)). 2021, 50 (44): 16364–16370. ISSN 1477-9226. doi:10.1039/d1dt02319e.
^ Yang, Chen; Zhang, Chong; Zheng, Zhansheng; Jiang, Chao; Luo, Jun; Du, Yang; Hu, Bingcheng; Sun, Chengguo; Christe, Karl O. Synthesis and Characterization of cyclo-Pentazolate Salts of NH₄⁺, NH₃OH⁺, N₂H₅⁺, C(NH₂)₃⁺, and N(CH₃)₄⁺. Journal of the American Chemical Society (American Chemical Society (ACS)). 2018-11-05, 140 (48): 16488–16494. ISSN 0002-7863. doi:10.1021/jacs.8b05106.
^ Xu, Yuangang; Zhou, Jianxin; Li, Dongxue; Wang, Pengcheng; Lin, Qiuhan; Lu, Ming. Hexaamminecobalt(III) Cation as Multiple Hydrogen Bond Donors: Synthesis, Characterization and Energetic Properties of cyclo-Pentazolate and Azide Based Complexes. Crystal Growth & Design (American Chemical Society (ACS)). 2022-12-27, 23 (2): 811–819. ISSN 1528-7483. doi:10.1021/acs.cgd.2c01066.

[Sun-1] 1.0 ^1.1 ^1.2 ^1.3 Sun, Chengguo; Zhang, Chong; Jiang, Chao; Yang, Chen; Du, Yang; Zhao, Yue; Hu, Bingcheng; Zheng, Zhansheng; Christe, Karl O. Synthesis of AgN5 and its extended 3D energetic framework. Nature Communications (Springer Science and Business Media LLC). 2018-03-28, 9 (1). ISSN 2041-1723. doi:10.1038/s41467-018-03678-y.

[2] Wang, Xieyang; Dong, Zhen; Yang, Rui; Zhou, Shengren; Ye, Zhiwen. Syntheses and Characterization of two cyclo‐pentazolate salts. Zeitschrift für anorganische und allgemeine Chemie (Wiley). 2021-01-27, 647 (6): 681–685. ISSN 0044-2313. doi:10.1002/zaac.202000309.

[3] Williams, Ashley S.; Nguyen Cong, Kien; Gonzalez, Joseph M.; Oleynik, Ivan I. Crystal structure of silver pentazolates AgN₅ and AgN₆. Dalton Transactions (Royal Society of Chemistry (RSC)). 2021, 50 (44): 16364–16370. ISSN 1477-9226. doi:10.1039/d1dt02319e.

[4] Yang, Chen; Zhang, Chong; Zheng, Zhansheng; Jiang, Chao; Luo, Jun; Du, Yang; Hu, Bingcheng; Sun, Chengguo; Christe, Karl O. Synthesis and Characterization of cyclo-Pentazolate Salts of NH₄⁺, NH₃OH⁺, N₂H₅⁺, C(NH₂)₃⁺, and N(CH₃)₄⁺. Journal of the American Chemical Society (American Chemical Society (ACS)). 2018-11-05, 140 (48): 16488–16494. ISSN 0002-7863. doi:10.1021/jacs.8b05106.

[5] Xu, Yuangang; Zhou, Jianxin; Li, Dongxue; Wang, Pengcheng; Lin, Qiuhan; Lu, Ming. Hexaamminecobalt(III) Cation as Multiple Hydrogen Bond Donors: Synthesis, Characterization and Energetic Properties of cyclo-Pentazolate and Azide Based Complexes. Crystal Growth & Design (American Chemical Society (ACS)). 2022-12-27, 23 (2): 811–819. ISSN 1528-7483. doi:10.1021/acs.cgd.2c01066.

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