亞鐵氰酸銫

亞鐵氰酸銫是一種配位化合物，化學式為Cs₄[Fe(CN)₆]。它可由亞鐵氰酸（通過鉀鹽經IR-120陽離子交換樹脂交換得到）和氫氧化銫（或碳酸銫^[1]）反應得到。^[2]Cs₄[Fe(CN)₄]在液氨中被氰化銨氧化，也能得到Cs₄[Fe(CN)₆]。^[3]它在590 °C開始分解，生成氰化亞鐵和氰化銫。^[4]

參考文獻[編輯]

^ Komissarova, P. D.; Krestovnikova, S. A. Cesium ferrocyanide. Metody Polucheniya Khimicheskikh Reaktivov i Preparatov, 1967. 16. 99-100. ISSN: 0539-5143
^ Basinski, Antoni; Szablewski, Lech. A new method of preparation of alkali ferro- and ferricyanides. Chemia Analityczna (Warsaw, Poland), 1966. 11 (1): 199-200. ISSN: 0009-2223.
^ Elaine S. Dodsworth, Peter J. O'Grady, David Nicholls, David Roberts. The reactions of iron(III) bromide and iron(II) thiocyanate with ammonia and their reductions with alkali metals in liquid-ammonia solutions of alkali metal cyanides. Polyhedron. 1987-01, 6 (6): 1191–1195 [2020-12-15]. doi:10.1016/S0277-5387(00)80868-2 （英語）.
^ Seifer, G. B. Thermal decomposition of ferrocyanides of alkali metals. Zhurnal Neorganicheskoi Khimii, 1962. 7: 1242-1246. ISSN: 0044-457X.