四甲基硫氫化銨

四甲基硫氫化銨
英文名	Tetramethylammonium hydrosulfide
別名	四甲基氫硫化銨
識別
CAS號	10408-32-9
性質
化學式	C4H13NS
摩爾質量	107.22 g·mol−1
外觀	白色粉末
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

四甲基硫氫化銨是一種季銨鹽，化學式為(CH₃)₄NHS，它可由四甲基氫氧化銨和硫化氫在無水甲醇中反應得到，它是白色潮解性粉末，對氧敏感，為避免其分解，它需要在3 °C儲存。^[1]它和三甲硫基硼在硫化氫中反應，可以得到[(CH₃)₄N][B(SCH₃)₃SH]。^[2]它和三硫化二銻在溶劑熱的條件下反應，生成(CH₃)₄N[Sb₃S₅]。^[3]

參考文獻[編輯]

^ J. D. Cotton, T. C. Waddington. Liquid hydrogen sulphide as an ionising solvent. Part I. Base analogues and their neutralisation with hydrogen halides. Journal of the Chemical Society A: Inorganic, Physical, Theoretical. 1966: 785 [2021-09-07]. ISSN 0022-4944. doi:10.1039/j19660000785 （英語）.
^ Heller, Gert; Eysenbach, Wolfgang. Interactions of boron containing compounds in liquid hydrogen sulfide（英文）. Int. Symp. Specific Interact. Mol. Ions, [Proc.], 3rd, 1976. 1. 201-203. CODEN:37IWAS. (註：另可參閱文獻doi:10.1021/ic50192a036)
^ J. B. Parise. An Antimony Sulfide with a Two-Dimensional, Intersecting System of Channels. Science. 1991-01-18, 251 (4991): 293–294 [2021-09-07]. ISSN 0036-8075. doi:10.1126/science.251.4991.293 （英語）.

[1] J. D. Cotton, T. C. Waddington. Liquid hydrogen sulphide as an ionising solvent. Part I. Base analogues and their neutralisation with hydrogen halides. Journal of the Chemical Society A: Inorganic, Physical, Theoretical. 1966: 785 [2021-09-07]. ISSN 0022-4944. doi:10.1039/j19660000785 （英語）.

[2] Heller, Gert; Eysenbach, Wolfgang. Interactions of boron containing compounds in liquid hydrogen sulfide（英文）. Int. Symp. Specific Interact. Mol. Ions, [Proc.], 3rd, 1976. 1. 201-203. CODEN:37IWAS. (註：另可參閱文獻doi:10.1021/ic50192a036)

[3] J. B. Parise. An Antimony Sulfide with a Two-Dimensional, Intersecting System of Channels. Science. 1991-01-18, 251 (4991): 293–294 [2021-09-07]. ISSN 0036-8075. doi:10.1126/science.251.4991.293 （英語）.

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