溴化鎘銫

溴化鎘銫
	IUPAC名; Caesium cadmium bromide
別名	Caesium tribromocadmate;
識別
CAS號	16593-55-8
性質
化學式	CsCdBr3
摩爾質量	485.028 g/mol g·mol⁻¹
外觀	白色或無色固體
密度	4.53 g/cm3
熔點	450 °C（723 K）
結構
晶體結構	立方
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

溴化鎘銫（CsCdBr₃）是一種合成晶體材料。它屬於AMX₃組（A = 鹼金屬，M = 二價金屬，X = 鹵素離子）。與大部分其他溴化物不同，CsCdBr₃不吸濕，^[2]因此它可以用作太陽能電池中的高效上轉換材料。^[3]因為它具有摻雜稀土金屬離子的單晶結構，它也可以用作激活激光媒質（英語：active laser medium）。它在可見光和紅外區非常透明，可以用作非線性光學晶體。^[4]

化學式為Cs₂CdBr₄的溴化鎘銫也已合成。^[5]

參考文獻

^ Persson, Kristin. 36 Materials Science. Materials Data on CsCdBr3 (SG:221) by Materials Project (Data Set). LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). 2014. doi:10.17188/1275593.
^ Barthem, R. B.; Buisson, R.; Vial, JC.; Chaminade, JP. ENERGY TRANSFER IN CsCdBr3 : Nd3+SYSTEM (PDF). Le Journal de Physique Colloques. 1985, 46: C7–113–C7–117 [2022-01-01]. doi:10.1051/jphyscol:1985722. （原始內容存檔 (PDF)於2022-01-01）.
^ Cockroft, Nigel J.; Jones, Glynn D.; Nguyen, Dinh C. Dynamics and spectroscopy of infrared-to-visible upconversion in erbium-doped cesium cadmium bromide (CsCdBr3:Er3+). Physical Review B. 1992, 45 (10): 5187–5198. Bibcode:1992PhRvB..45.5187C. PMID 10000233. doi:10.1103/PhysRevB.45.5187.
^ Ren, Peng; Qin, Jingui; Chen, Chuangtian. A Novel Nonlinear Optical Crystal for the IR Region: Noncentrosymmetrically Crystalline CsCdBr3and its Properties. Inorganic Chemistry. 2003, 42 (1): 8–10. PMID 12513072. doi:10.1021/ic025813y.
^ Altermatt, D.; Arend, H.; Gramlich, V.; Niggli, A.; Petter, W. Low-temperature phases in Cs2CdBr4and Cs2HgBr4. Acta Crystallographica Section B. 1984, 40 (4): 347–350. doi:10.1107/S0108768184002275.

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[1] Persson, Kristin. 36 Materials Science. Materials Data on CsCdBr3 (SG:221) by Materials Project (Data Set). LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). 2014. doi:10.17188/1275593.

[2] Barthem, R. B.; Buisson, R.; Vial, JC.; Chaminade, JP. ENERGY TRANSFER IN CsCdBr3 : Nd3+SYSTEM (PDF). Le Journal de Physique Colloques. 1985, 46: C7–113–C7–117 [2022-01-01]. doi:10.1051/jphyscol:1985722. （原始內容存檔 (PDF)於2022-01-01）.

[3] Cockroft, Nigel J.; Jones, Glynn D.; Nguyen, Dinh C. Dynamics and spectroscopy of infrared-to-visible upconversion in erbium-doped cesium cadmium bromide (CsCdBr3:Er3+). Physical Review B. 1992, 45 (10): 5187–5198. Bibcode:1992PhRvB..45.5187C. PMID 10000233. doi:10.1103/PhysRevB.45.5187.

[4] Ren, Peng; Qin, Jingui; Chen, Chuangtian. A Novel Nonlinear Optical Crystal for the IR Region: Noncentrosymmetrically Crystalline CsCdBr3and its Properties. Inorganic Chemistry. 2003, 42 (1): 8–10. PMID 12513072. doi:10.1021/ic025813y.

[5] Altermatt, D.; Arend, H.; Gramlich, V.; Niggli, A.; Petter, W. Low-temperature phases in Cs2CdBr4and Cs2HgBr4. Acta Crystallographica Section B. 1984, 40 (4): 347–350. doi:10.1107/S0108768184002275.

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