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1-金剛烷硫醇

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1-金剛烷硫醇
識別
CAS號 34301-54-7  checkY
SMILES
 
  • SC12CC3CC(CC(C3)C1)C2
性質
化學式 C10H16S
摩爾質量 168.3 g·mol−1
外觀 白色固體[1]
熔點 100-102 °C[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

1-金剛烷硫醇是一種有機硫化合物,化學式為C10H15SH。它可由1-溴金剛烷硫脲氫溴酸和冰乙酸回流反應,再經氫氧化鈉水解、鹽酸酸化得到;[1]或由1-金剛烷醇勞森試劑反應製得。[2]它可以被高錳酸鉀氧化為二(1-金剛烷基)二硫。[3]

參考文獻

[編輯]
  1. ^ 1.0 1.1 1.2 Studies on the diastereoselective oxidation of 1-thio-β-D-glucopyranosides: synthesis of the usually less favoured RS sulfoxide as a single diastereoisomer. Organic & Biomolecular Chemistry, 2015. doi:10.1039/C4OB02030H
  2. ^ S-alkyl Dithiocarbamates Synthesis through Electrochemical Multicomponent Reaction of Thiols, Hydrogen Sulfide, and Isocyanides. J. Org. Chem. 2023, 88, 17, 12311–12318. doi:10.1021/acs.joc.3c01017
  3. ^ Ground solid permanganate oxidative coupling of thiols into symmetrical/unsymmetrical disulfides: selective and improved process. Journal of Sulfur Chemistry, 2022. 43 (6). doi:10.1080/17415993.2022.2083914