4,4'-偶氮吡啶
外觀
4,4'-偶氮吡啶 | |
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識別 | |
CAS號 | 2632-99-7 ![]() |
性質 | |
化學式 | C10H8N4 |
摩爾質量 | 184.2 g·mol−1 |
外觀 | 橙色針狀晶體 |
熔點 | 107—108 °C(380—381 K)[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
4,4'-偶氮吡啶是一種有機化合物,化學式為C10H8N4。它可由4-氨基吡啶和10%次氯酸鈉溶液反應製得,[1]或由1,2-二(4-吡啶基)肼和氧氣在DMF中於80 °C反應得到。[2]它和氰化鎳在甲苯中回流反應,可以得到四氰合鎳(II)酸(4,4'-偶氮吡啶)合鎳(II)。[3]它和五羰基氯化錸在四氫呋喃/甲苯中回流反應,可以得到三羰基(4,4'-偶氮吡啶)氯化錸四聚體。[4]
參考文獻
[編輯]- ^ 1.0 1.1 Jean Pierre Launay, Myriam Tourrel-Pagis, Jean Francois Lipskier, Valerie Marvaud, Christian Joachim. Control of intramolecular electron transfer by a chemical reaction. The 4,4'-azopyridine/1,2-bis(4-pyridyl)hydrazine system. Inorganic Chemistry. 1991-03, 30 (5): 1033–1038 [2022-11-07]. ISSN 0020-1669. doi:10.1021/ic00005a029. (原始內容存檔於2022-11-07) (英語).
- ^ Yu Lin, Hao Wu, Ziang Liu, Jin Li, Rui Cai, Makoto Hashimoto, Lei Wang. Additive-free aerobic oxidation of hydroazobenzenes: Access to azobenzenes and epoxidation of enones. Tetrahedron Letters. 2022-10, 108: 154132 [2022-11-07]. doi:10.1016/j.tetlet.2022.154132 (英語).
- ^ Jeffrey T. Culp, Catherine Madden, Kristi Kauffman, Fan Shi, Christopher Matranga. Screening Hofmann Compounds as CO 2 Sorbents: Nontraditional Synthetic Route to Over 40 Different Pore-Functionalized and Flexible Pillared Cyanonickelates. Inorganic Chemistry. 2013-04-15, 52 (8): 4205–4216 [2022-11-07]. ISSN 0020-1669. doi:10.1021/ic301893p. (原始內容存檔於2022-11-07) (英語).
- ^ Shih-Sheng Sun, Alistair J. Lees. Self-Assembly Triangular and Square Rhenium(I) Tricarbonyl Complexes: A Comprehensive Study of Their Preparation, Electrochemistry, Photophysics, Photochemistry, and Host−Guest Properties. Journal of the American Chemical Society. 2000-09-01, 122 (37): 8956–8967 [2022-11-07]. ISSN 0002-7863. doi:10.1021/ja001677p. (原始內容存檔於2022-11-07) (英語).