苄基三乙基氯化銨

苄基三乙基氯化銨
識別
CAS號	56-37-1
性質
化學式	C13H22ClN
摩爾質量	227.77 g·mol−1
外觀	無色晶體
溶解性（水）	易溶
相關物質
其他陰離子	苄基三乙基溴化銨
其他陽離子	苄基三甲基氯化銨（德語：Benzyltrimethylammoniumchlorid）
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

苄基三乙基氯化銨（TEBAC，BTEAC）是一種季銨鹽，化學式為C₁₃H₂₂ClN。它可由三乙胺和氯化苄在氧化鎳納米顆粒的催化下加熱反應得到。^[1]它和碲氫化鈉在二甲基甲酰胺中反應，生成三乙胺。^[2]它可以和金屬鹵化物反應，生成相應鹵配合物的季銨鹽。^[3]^[4]它在有機合成中可用作相轉移催化劑^[5]和苄基化試劑。^[6]

參考文獻[編輯]

^ Kang Hyun Park, Il Gu Jung, Young Keun Chung, Jin Wook Han. Activation of CCl Bonds in Chloroalkanes by Nickel Oxide Nanoparticles: Formation of Tetrasubstituted Ammonium Salts from Tertiary Amines. Advanced Synthesis & Catalysis. 2007-02-05, 349 (3): 411–416 [2022-03-08]. doi:10.1002/adsc.200600305. （原始內容存檔於2022-03-08）（英語）.
^ Weixing Li, Xun-Jun Zhou. The Reaction Between Sodium Hydrogen Telluride and Phase Transfer Catalysts. Synthetic Communications. 1995-11, 25 (22): 3635–3639 [2022-03-08]. ISSN 0039-7911. doi:10.1080/00397919508015499 （英語）.
^ E. S. Putilova, G. V. Kryshtal』, G. M. Zhdankina, N. A. Troitskii, S. G. Zlotin. Alkylammonium and Alkylimidazolium Perhaloborates, Phosphates, and Aluminates as Catalysts in the Biginelli Reaction. Russian Journal of Organic Chemistry. 2005-04, 41 (4): 512–516 [2022-03-08]. ISSN 1070-4280. doi:10.1007/s11178-005-0196-9 （英語）.
^ Emmanuel Robé, Sébastien Maria, Philippe Richard, Rinaldo Poli. Mixed Titanium–Hafnium Chloridometallate Complexes. European Journal of Inorganic Chemistry. 2007-06, 2007 (17): 2434–2442 [2022-03-08]. ISSN 1434-1948. doi:10.1002/ejic.200700056 （英語）.
^ Masayuki Nakajima, John C. Warner, J.-P. Anselme. N-nitrosamines the phase-transfer mediated nitrosation of secondary amines with sodium nitrite and n-haloamides. Tetrahedron Letters. 1984-01, 25 (25): 2619–2622 [2022-03-08]. doi:10.1016/S0040-4039(01)81245-4. （原始內容存檔於2018-06-29）（英語）.
^ A. Khalafi-Nezhad, A. Zare, A. Parhami, A. Hasaninejad, A. R. Moosavi Zare. Quaternary ammonium salts as highly efficient and green alkylating agents for N-alkylation of azaheterocycles under microwave irradiation. Journal of the Iranian Chemical Society. 2008-10, 5 (S1): S40–S46 [2022-03-08]. ISSN 1735-207X. doi:10.1007/BF03246487 （英語）.

[1] Kang Hyun Park, Il Gu Jung, Young Keun Chung, Jin Wook Han. Activation of CCl Bonds in Chloroalkanes by Nickel Oxide Nanoparticles: Formation of Tetrasubstituted Ammonium Salts from Tertiary Amines. Advanced Synthesis & Catalysis. 2007-02-05, 349 (3): 411–416 [2022-03-08]. doi:10.1002/adsc.200600305. （原始內容存檔於2022-03-08）（英語）.

[2] Weixing Li, Xun-Jun Zhou. The Reaction Between Sodium Hydrogen Telluride and Phase Transfer Catalysts. Synthetic Communications. 1995-11, 25 (22): 3635–3639 [2022-03-08]. ISSN 0039-7911. doi:10.1080/00397919508015499 （英語）.

[3] E. S. Putilova, G. V. Kryshtal』, G. M. Zhdankina, N. A. Troitskii, S. G. Zlotin. Alkylammonium and Alkylimidazolium Perhaloborates, Phosphates, and Aluminates as Catalysts in the Biginelli Reaction. Russian Journal of Organic Chemistry. 2005-04, 41 (4): 512–516 [2022-03-08]. ISSN 1070-4280. doi:10.1007/s11178-005-0196-9 （英語）.

[4] Emmanuel Robé, Sébastien Maria, Philippe Richard, Rinaldo Poli. Mixed Titanium–Hafnium Chloridometallate Complexes. European Journal of Inorganic Chemistry. 2007-06, 2007 (17): 2434–2442 [2022-03-08]. ISSN 1434-1948. doi:10.1002/ejic.200700056 （英語）.

[5] Masayuki Nakajima, John C. Warner, J.-P. Anselme. N-nitrosamines the phase-transfer mediated nitrosation of secondary amines with sodium nitrite and n-haloamides. Tetrahedron Letters. 1984-01, 25 (25): 2619–2622 [2022-03-08]. doi:10.1016/S0040-4039(01)81245-4. （原始內容存檔於2018-06-29）（英語）.

[6] A. Khalafi-Nezhad, A. Zare, A. Parhami, A. Hasaninejad, A. R. Moosavi Zare. Quaternary ammonium salts as highly efficient and green alkylating agents for N-alkylation of azaheterocycles under microwave irradiation. Journal of the Iranian Chemical Society. 2008-10, 5 (S1): S40–S46 [2022-03-08]. ISSN 1735-207X. doi:10.1007/BF03246487 （英語）.

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