Sar配體

Sar配體
	IUPAC名; 3,6,10,13,16,19-Hexazabicyclo[6.6.6]icosane
別名	3,6,10,13,16,19-六氮雜雙環[6.6.6]二十烷
識別
CAS號	64189-50-0
PubChem	6394006
ChemSpider	4908238
SMILES	C1CNCC2CNCCNCC(CN1)CNCCNC2;
InChI	1S/C14H32N6/c1-2-16-8-14-11-19-5-3-17-9-13(7-15-1)10-18-4-6-20-12-14/h13-20H,1-12H2;
InChIKey	NVOVSXGZALWAFS-UHFFFAOYSA-N
性質
化學式	C14H32N6
摩爾質量	284.44 g·mol−1
密度	0.911±0.06 g·cm−3
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

Sar（3,6,10,13,16,19-六氮雜雙環[6.6.6]二十烷）是一種有機化合物，化學式為C₁₄H₃₂N₆。它可由三氯化三(乙二胺)合鈷(III)、硝基甲烷和甲醛在鹼性條件下反應，得到配位鈷(III)的硝基配體，經還原、氯化、二次還原、配體取代（CN⁻取代sar）後將其萃取得到。^[2]它可以和金屬形成螯合物。^[3]

參考文獻[編輯]

^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 ((C) 1994-2021 ACD/Labs). Retrieved from SciFinder. [2021-09-25].
^ Ga Bottomley, Ij Clark, Ii Creaser, Lm Engelhardt, Rj Geue, Ks Hagen, Jm Harrowfield, Ga Lawrance, Pa Lay, Am Sargeson, Aj See, Bw Skelton, Ah White, Fr Wilner. The Synthesis and Structure of Encapsulating Ligands: Properties of Bicyclic Hexamines. Australian Journal of Chemistry. 1994, 47 (1): 143 [2021-09-25]. ISSN 0004-9425. doi:10.1071/CH9940143 （英語）.
^ J. Mroziński, A. Skorupa, A. Pochaba, Y. Dromzée, M. Verdaguer, E. Goovaerts, H. Varcammen, B. Korybut-Daszkiewicz. Sarcophagine Ni(II) diperchlorate: synthesis, crystallographic structure, magnetism and high-field EPR. Journal of Molecular Structure. 2001-01, 559 (1-3): 107–118 [2021-09-25]. doi:10.1016/S0022-2860(00)00696-7. （原始內容存檔於2020-02-11）（英語）.

[1] Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 ((C) 1994-2021 ACD/Labs). Retrieved from SciFinder. [2021-09-25].

[2] Ga Bottomley, Ij Clark, Ii Creaser, Lm Engelhardt, Rj Geue, Ks Hagen, Jm Harrowfield, Ga Lawrance, Pa Lay, Am Sargeson, Aj See, Bw Skelton, Ah White, Fr Wilner. The Synthesis and Structure of Encapsulating Ligands: Properties of Bicyclic Hexamines. Australian Journal of Chemistry. 1994, 47 (1): 143 [2021-09-25]. ISSN 0004-9425. doi:10.1071/CH9940143 （英語）.

[3] J. Mroziński, A. Skorupa, A. Pochaba, Y. Dromzée, M. Verdaguer, E. Goovaerts, H. Varcammen, B. Korybut-Daszkiewicz. Sarcophagine Ni(II) diperchlorate: synthesis, crystallographic structure, magnetism and high-field EPR. Journal of Molecular Structure. 2001-01, 559 (1-3): 107–118 [2021-09-25]. doi:10.1016/S0022-2860(00)00696-7. （原始內容存檔於2020-02-11）（英語）.

[1]

[2]

[3]