三氟甲磺酸五氟苯铵
三氟甲磺酸五氟苯铵 | |
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识别 | |
CAS号 | 912823-79-1 ![]() |
性质 | |
化学式 | C7H3F8NO3S |
摩尔质量 | 333.16 g·mol−1 |
外观 | 无色晶体[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
三氟甲磺酸五氟苯铵是五氟苯胺的三氟甲磺酸盐,可用作羧酸酯、硫酯和内酯形成,以及酯交换反应的催化剂。[1]它也能催化里特反应。[2]它可由化学计量比的五氟苯胺和三氟甲磺酸反应制得:[1]
参考文献[编辑]
- ^ 1.0 1.1 1.2 Funatomi, Takashi; Wakasugi, Kazunori; Misaki, Tomonori; Tanabe, Yoo. Pentafluorophenylammonium triflate (PFPAT): an efficient, practical, and cost-effective catalyst for esterification, thioesterification, transesterification, and macrolactone formation. Green Chemistry (Royal Society of Chemistry (RSC)). 2006, 8 (12): 1022. ISSN 1463-9262. doi:10.1039/b609181b.
- ^ Khaksar, Samad; Fattahi, Eskandar; Fattahi, Esmail. Organocatalytic synthesis of amides from nitriles via the Ritter reaction. Tetrahedron Letters (Elsevier BV). 2011, 52 (45): 5943–5946. ISSN 0040-4039. doi:10.1016/j.tetlet.2011.08.121.