异土木香内酯
外观
异土木香内酯 | |
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IUPAC名 (3aR,4aS,8aR,9aR)-Decahydro-8a-methyl-3,5-bis(methylene)naphtho[2,3-b]furan-2(3H)-one | |
英文名 | isoalantolactone |
识别 | |
CAS号 | 470-17-7 |
PubChem | 73285 |
ChemSpider | 66028 |
SMILES |
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InChI |
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InChIKey | CVUANYCQTOGILD-QVHKTLOISA-N |
ChEBI | 5981 |
性质 | |
化学式 | C15H20O2 |
摩尔质量 | 232.32 g·mol−1 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
异土木香内酯是一种有机化合物,化学式C15H20O2,可见于土木香[1][2]、大叶土木香[3][4]、旋覆花[5][6]等物种。它和苯硫酚在三乙胺存在下反应,可以得到3位亚甲基(羰基旁碳连接的亚甲基)被苯硫基甲基取代的产物。[7]
参考资料
[编辑]- ^ Cantrell CL; Abate L; Fronczek FR; Quijano L; Fischer NH. Antimycobacterial eudesmanolides from Inula helenium and Rudbeckia subtomentosa. Planta Medica. 1999-05, 65 (4). doi:10.1055/S-1999-14001 (英语).
- ^ Tenji Konishi; Yasuo Shimada; Tsuneatsu Nagao; Hikaru Okabe; Takao Konoshima. Antiproliferative sesquiterpene lactones from the roots of Inula helenium. Biological and Pharmaceutical Bulletin. 2002, 25 (10). doi:10.1248/BPB.25.1370.
- ^ S. A. Lugovskaya; N. V. Plekhanova; K. Yu. Orozbaev. Alantolactone from Inula grandis. Chemistry of Natural Compounds. 2004-12, 12 (1). doi:10.1007/BF00570217.
- ^ Charles L Cantrell; Julia W Pridgeon; Frank R Fronczek. Structure-activity relationship studies on derivatives of eudesmanolides from Inula helenium as toxicants against Aedes aegypti larvae and adults. Chemistry and Biodiversity. 2010-07, 7 (7). doi:10.1002/CBDV.201000031 (英语).
- ^ Chao Yang; Chun-Ming Wang; Zhong-Jian Jia. Sesquiterpenes and other constituents from the aerial parts of Inula japonica. Planta Medica. 2003-07, 69 (7). doi:10.1055/S-2003-41123.
- ^ Charles L Cantrell; Julia W Pridgeon; Frank R Fronczek. Structure-activity relationship studies on derivatives of eudesmanolides from Inula helenium as toxicants against Aedes aegypti larvae and adults. Chemistry and Biodiversity. 2010-07, 7 (7). doi:10.1002/CBDV.201000031 (英语).
- ^ Semakov, A. V.; Klochkov, S. G. (2020). Addition Products of Thiophenol and Selenophenol to Inula Helenium Lactones. Chemistry of Natural Compounds, 56(2), 254–256. doi:10.1007/s10600-020-03000-7
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