乙酸铀酰锌钠

乙酸铀酰锌钠
英文名	Sodium uranyl zinc acetate
识别
CAS号	39395-63-6（无水） ; 2020022-02-8（六水）
SMILES	[Na+].[Zn+2].O=[U+2]=O.CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].O=[U+2]=O.CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].O=[U+2]=O.CC(=O)[O-].CC(=O)[O-].CC(=O)[O-];
性质
化学式	NaZn(UO2)3(C2H3O2)9
外观	黄色晶体（六水）
溶解性（水）	难溶
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

乙酸铀酰锌钠是一种配位化合物，化学式为NaZn(UO₂)₃(C₂H₃O₂)₉，分子中存在配阴离子UO₂(C₂H₃O₂)₃⁻。^[1]X射线单晶衍射表明，它的六水合物由[Zn(H₂O)₆]²⁺和{Na[UO₂(CH₃COO)₃]₃}²⁻构成。^[2]它可由乙酸铀酰、乙酸锌和乙酸在水中将Na⁺沉淀产生，并可用于Na⁺的重量分析。^[3]它在360~674 °C分解为2ZnU₂O₇·Na₂U₂O₇。^[4]

参考文献

^ G. L. Caldow, A. B. Van Cleave, R. L. Eager. THE INFRARED SPECTRA OF SOME URANYL COMPOUNDS. Canadian Journal of Chemistry. 1960-06-01, 38 (6): 772–782 [2020-09-10]. ISSN 0008-4042. doi:10.1139/v60-112 （英语）.
^ Vladislav V. Klepov, Larisa B. Serezhkina, Victor N. Serezhkin, Evgeny V. Alekseev. Synthesis and crystal structure analysis of uranyl triple acetates. Journal of Solid State Chemistry. 2016-12, 244: 100–107 [2020-09-10]. doi:10.1016/j.jssc.2016.09.019. （原始内容存档于2020-02-18）（英语）.
^ H. H. Barber, I. M. Kolthoff. A SPECIFIC REAGENT FOR THE RAPID GRAVIMETRIC DETERMINATION OF SODIUM. Journal of the American Chemical Society. 1928-06, 50 (6): 1625–1631 [2020-09-10]. ISSN 0002-7863. doi:10.1021/ja01393a014. （原始内容存档于2019-12-05）（英语）.
^ Duval, Therese; Duval, Clement. The thermogravimetry of analytical precipitates. VIII. Determination of sodium. Analytica Chimica Acta, 1948 (2): 97-102. ISSN: 0003-2670. doi:10.1016/S0003-2670(01)93774-2.

[1] G. L. Caldow, A. B. Van Cleave, R. L. Eager. THE INFRARED SPECTRA OF SOME URANYL COMPOUNDS. Canadian Journal of Chemistry. 1960-06-01, 38 (6): 772–782 [2020-09-10]. ISSN 0008-4042. doi:10.1139/v60-112 （英语）.

[2] Vladislav V. Klepov, Larisa B. Serezhkina, Victor N. Serezhkin, Evgeny V. Alekseev. Synthesis and crystal structure analysis of uranyl triple acetates. Journal of Solid State Chemistry. 2016-12, 244: 100–107 [2020-09-10]. doi:10.1016/j.jssc.2016.09.019. （原始内容存档于2020-02-18）（英语）.

[3] H. H. Barber, I. M. Kolthoff. A SPECIFIC REAGENT FOR THE RAPID GRAVIMETRIC DETERMINATION OF SODIUM. Journal of the American Chemical Society. 1928-06, 50 (6): 1625–1631 [2020-09-10]. ISSN 0002-7863. doi:10.1021/ja01393a014. （原始内容存档于2019-12-05）（英语）.

[4] Duval, Therese; Duval, Clement. The thermogravimetry of analytical precipitates. VIII. Determination of sodium. Analytica Chimica Acta, 1948 (2): 97-102. ISSN: 0003-2670. doi:10.1016/S0003-2670(01)93774-2.

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