2-氟-3-氯-6-溴碘苯

2-氟-3-氯-6-溴碘苯
别名	1-溴-4-氯-3-氟-2-碘苯
识别
CAS号	1820674-47-2
PubChem	98041501
SMILES	FC=1C(Cl)=CC=C(Br)C1I;
性质
化学式	C6H2BrClFI
摩尔质量	335.34 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

2-氟-3-氯-6-溴碘苯是一种有机化合物，化学式为C₆H₂BrClFI，它是氟氯溴碘苯的同分异构体之一。它和5-甲酰基-1,3-苯并二𫫇茂-6-硼酸频哪醇酯在磷酸钾存在下、二氯化双(三苯基膦)钯催化下反应，可以得到6-(2-氟-3-氯-6-溴苯基)-1,3-苯并二𫫇茂-5-甲醛。^[1]它和3-羟基萘-2-硼酸在二(三叔丁基膦)钯催化下反应，可以得到4-氯-1-溴苯并[b]萘并[2,3-d]呋喃。^[2]

参考文献

^ Yuan-Ye Jhang, Tai-Ting Fan-Chiang, Jun-Min Huang, and Jen-Chieh Hsieh. Copper-Catalyzed Annulation: A Method for the Systematic Synthesis of Phenanthridinium Bromide. Org. Lett. 2016, 18, 5, 1154–1157. doi:10.1021/acs.orglett.6b00269.
^ Kim, Minjun; et al. Preparation of heteroaromatic compounds as organic electroluminescent device materials. WO2021235830 A1 2021-11-25.

[1] Yuan-Ye Jhang, Tai-Ting Fan-Chiang, Jun-Min Huang, and Jen-Chieh Hsieh. Copper-Catalyzed Annulation: A Method for the Systematic Synthesis of Phenanthridinium Bromide. Org. Lett. 2016, 18, 5, 1154–1157. doi:10.1021/acs.orglett.6b00269.

[2] Kim, Minjun; et al. Preparation of heteroaromatic compounds as organic electroluminescent device materials. WO2021235830 A1 2021-11-25.

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