八氟合氙(VI)酸亞硝醯

八氟合氙(VI)酸亞硝醯
	IUPAC名; Nitrosonium octafluoroxenate(VI)
識別
CAS號	17501-82-5
SMILES	N#[O+].N#[O+].F[Xe-2](F)(F)(F)(F)(F)(F)F;
性質
化學式	(NO); 2XeF; 8
密度	3.354 g/cm³
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

八氟合氙(VI)酸亞硝醯（(NO)
2XeF
8），是由亞硝醯離子（NO⁺）與八氟合氙(VI)酸根離子（XeF₈²⁻）結合而成的化合物。其中 XeF₈²⁻ 離子為方形反稜柱分子構型，Xe-F 鍵長分別為 1.971 Å、1.946 Å、1.958 Å、2.052 Å 和 2.099 Å。^[1]它可通過六氟化氙與亞硝醯氟反應製取。^[2]

XeF
6 + 2 NOF → (NO)
2XeF
8

類似化合物還有八氟合氙(VI)酸的鹼金屬鹽類，例如 Cs₂XeF₈ 和 Rb₂XeF₈，它們在400°C以下都是穩定的。^[3]^[4]

參考資料[編輯]

^ Peterson, W.; Holloway, H.; Coyle, A.; Williams, M. Antiprismatic Coordination about Xenon: the Structure of Nitrosonium Octafluoroxenate(VI). Science (New York, N.Y.). Sep 1971, 173 (4003): 1238–1239. ISSN 0036-8075. PMID 17775218. doi:10.1126/science.173.4003.1238.
^ Cotton (2007). Advanced Inorganic Chemistry (6th ed.). Wiley-India. p. 588. ISBN 8126513381.
^ Chandra, Sulekh (2004). Comprehensive Inorganic Chemistry. New Age International. p. 308. ISBN 8122415121.
^ Holleman, A. F.; Wiberg,, E. (2001). Inorganic Chemistry. San Diego: Academic Press. ISBN 0-12-352651-5.

[1] Peterson, W.; Holloway, H.; Coyle, A.; Williams, M. Antiprismatic Coordination about Xenon: the Structure of Nitrosonium Octafluoroxenate(VI). Science (New York, N.Y.). Sep 1971, 173 (4003): 1238–1239. ISSN 0036-8075. PMID 17775218. doi:10.1126/science.173.4003.1238.

[2] Cotton (2007). Advanced Inorganic Chemistry (6th ed.). Wiley-India. p. 588. ISBN 8126513381.

[chandra-3] Chandra, Sulekh (2004). Comprehensive Inorganic Chemistry. New Age International. p. 308. ISBN 8122415121.

[holleman1-4] Holleman, A. F.; Wiberg,, E. (2001). Inorganic Chemistry. San Diego: Academic Press. ISBN 0-12-352651-5.

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