三(乙烯)合铂

三(乙烯)合铂
识别
CAS号	56009-87-1
性质
化学式	C6H12Pt
摩尔质量	279.24 g·mol−1
外观	白色晶体
密度	2.79 g·cm−3（190 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

三(乙烯)合铂是一种有机铂化合物，化学式为Pt(C₂H₄)₃，它在溶液中不稳定。它可由双(1,5-环辛二烯)合铂和乙烯在室温反应得到。^[1]它和四氟乙烯反应，可以得到更稳定的二(乙烯)四氟乙烯合铂（Pt(C₂F₂)(C₂H₄)₂）。^[3]它和氧气在−46 °C于溶液中反应，可以得到双氧配合物Pt(O₂)(C₂H₄)₂。^[4]

参考文献

^ ^1.0 ^1.1 Michael Green, Judith A. Howard, John L. Spencer, F. Gordon A. Stone. Ligand exchange reactions of bis(cyclo-octa-1,5-diene)platinum; synthesis of trisethyleneplatinum and molecular structure of tris-µ-(t-butyl isocyanide)-tris-(t-butyl isocyanide)-triangulo-triplatinum, [Pt 3 (Bu t NC) 6 ]. J. Chem. Soc., Chem. Commun. 1975, (1): 3–4 [2021-12-10]. ISSN 0022-4936. doi:10.1039/C39750000003 （英语）.
^ X-ray and neutron diffraction studies of the crystal and molecular structures of tris(ethylene)platinum and bis(ethylene)(tetrafluoroethylene)platinum. Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences. 1983-03-08, 386 (1790): 145–161 [2021-12-10]. ISSN 0080-4630. doi:10.1098/rspa.1983.0029. （原始内容存档于2021-12-10）（英语）.
^ Michael Green, Judith A. K. Howard, John L. Spencer, F. Gordon A. Stone. Syntheses of palladium(0) and platinum(0) olefin complexes; molecular structures of [Pt(C2F4)(C2H4)2] and tris(bicyclo[2.2.1]heptene)platinum. Journal of the Chemical Society, Chemical Communications. 1975, (11): 449 [2021-12-10]. ISSN 0022-4936. doi:10.1039/c39750000449 （英语）.
^ Wen-Shu Hwang. Dioxygen adduct complex of bis(ethylene)platinum(0) : Formation and characterization. Polyhedron. 1984-01, 3 (4): 513–514 [2021-12-10]. doi:10.1016/S0277-5387(00)84529-5. （原始内容存档于2018-06-18）（英语）.

[jcscc-1] 1.0 ^1.1 Michael Green, Judith A. Howard, John L. Spencer, F. Gordon A. Stone. Ligand exchange reactions of bis(cyclo-octa-1,5-diene)platinum; synthesis of trisethyleneplatinum and molecular structure of tris-µ-(t-butyl isocyanide)-tris-(t-butyl isocyanide)-triangulo-triplatinum, [Pt 3 (Bu t NC) 6 ]. J. Chem. Soc., Chem. Commun. 1975, (1): 3–4 [2021-12-10]. ISSN 0022-4936. doi:10.1039/C39750000003 （英语）.

[2] X-ray and neutron diffraction studies of the crystal and molecular structures of tris(ethylene)platinum and bis(ethylene)(tetrafluoroethylene)platinum. Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences. 1983-03-08, 386 (1790): 145–161 [2021-12-10]. ISSN 0080-4630. doi:10.1098/rspa.1983.0029. （原始内容存档于2021-12-10）（英语）.

[3] Michael Green, Judith A. K. Howard, John L. Spencer, F. Gordon A. Stone. Syntheses of palladium(0) and platinum(0) olefin complexes; molecular structures of [Pt(C2F4)(C2H4)2] and tris(bicyclo[2.2.1]heptene)platinum. Journal of the Chemical Society, Chemical Communications. 1975, (11): 449 [2021-12-10]. ISSN 0022-4936. doi:10.1039/c39750000449 （英语）.

[4] Wen-Shu Hwang. Dioxygen adduct complex of bis(ethylene)platinum(0) : Formation and characterization. Polyhedron. 1984-01, 3 (4): 513–514 [2021-12-10]. doi:10.1016/S0277-5387(00)84529-5. （原始内容存档于2018-06-18）（英语）.

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