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三(乙烯)合铂

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三(乙烯)合铂
识别
CAS号 56009-87-1  checkY
性质
化学式 C6H12Pt
摩尔质量 279.24 g·mol−1
外观 白色晶体[1]
密度 2.79 g·cm−3(190 K)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

三(乙烯)合铂是一种有机铂化合物,化学式为Pt(C2H4)3,它在溶液中不稳定。它可由双(1,5-环辛二烯)合铂乙烯室温反应得到。[1]它和四氟乙烯反应,可以得到更稳定的二(乙烯)四氟乙烯合铂(Pt(C2F2)(C2H4)2)。[3]它和氧气在−46 °C于溶液中反应,可以得到双氧配合物Pt(O2)(C2H4)2[4]

参考文献

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  1. ^ 1.0 1.1 Michael Green, Judith A. Howard, John L. Spencer, F. Gordon A. Stone. Ligand exchange reactions of bis(cyclo-octa-1,5-diene)platinum; synthesis of trisethyleneplatinum and molecular structure of tris-µ-(t-butyl isocyanide)-tris-(t-butyl isocyanide)-triangulo-triplatinum, [Pt 3 (Bu t NC) 6 ]. J. Chem. Soc., Chem. Commun. 1975, (1): 3–4 [2021-12-10]. ISSN 0022-4936. doi:10.1039/C39750000003 (英语). 
  2. ^ X-ray and neutron diffraction studies of the crystal and molecular structures of tris(ethylene)platinum and bis(ethylene)(tetrafluoroethylene)platinum. Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences. 1983-03-08, 386 (1790): 145–161 [2021-12-10]. ISSN 0080-4630. doi:10.1098/rspa.1983.0029. (原始内容存档于2021-12-10) (英语). 
  3. ^ Michael Green, Judith A. K. Howard, John L. Spencer, F. Gordon A. Stone. Syntheses of palladium(0) and platinum(0) olefin complexes; molecular structures of [Pt(C2F4)(C2H4)2] and tris(bicyclo[2.2.1]heptene)platinum. Journal of the Chemical Society, Chemical Communications. 1975, (11): 449 [2021-12-10]. ISSN 0022-4936. doi:10.1039/c39750000449 (英语). 
  4. ^ Wen-Shu Hwang. Dioxygen adduct complex of bis(ethylene)platinum(0) : Formation and characterization. Polyhedron. 1984-01, 3 (4): 513–514 [2021-12-10]. doi:10.1016/S0277-5387(00)84529-5. (原始内容存档于2018-06-18) (英语).