二氢黄樟素
| 二氢黄樟素 | |
|---|---|
| |
| 识别 | |
| CAS号 | 94-58-6 
|
| PubChem | 7197 |
| ChemSpider | 6929 |
| SMILES |
|
| 性质 | |
| 化学式 | C10H12O2 |
| 摩尔质量 | 164.2 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
二氢黄樟素是一种有机化合物，化学式为C10H12O2。它可由黄樟素或异黄樟素在三氯化钌水合物等催化剂催化下由硼氢化钠反应得到。[1][2]它在1,4-萘二甲腈存在下于乙腈水溶液中光照反应，可以得到5-丙酰基苯并二𫫇茂。[3]
参考文献[编辑]
- ^ Sharma, Pawan K.; Kumar, Surender; Kumar, Pawan; Nielsen, Poul. Selective reduction of mono- and disubstituted olefins by NaBH4 and catalytic RuCl3. Tetrahedron Letters. 2007, 48 (49): 8704–8708. doi:10.1016/j.tetlet.2007.10.017.
- ^ Narisada, Masayuki; Horibe, Isao; Watanabe, Fumihiko; Takeda, Kenichi. Selective reduction of aryl halides and .alpha.,.beta.-unsaturated esters with sodium borohydride-cuprous chloride in methanol and its application to deuterium labeling. The Journal of Organic Chemistry. 1989, 54 (22): 5308–5313. ISSN 0022-3263. doi:10.1021/jo00283a025.
- ^ Pandey, Ganesh; Pal, Sujit; Laha, Ramkrishna. Direct Benzylic C-H Activation for C=O Bond Formation by Photoredox Catalysis. Angewandte Chemie International Edition. 2013-05-03, 52 (19): 5146–5149. ISSN 1433-7851. doi:10.1002/anie.201210333.