双(三苯基膦)叠氮化亚铵
外观
双(三苯基膦)叠氮化亚铵 | |
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识别 | |
CAS号 | 38011-36-8 ![]() |
SMILES |
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性质 | |
化学式 | C36H30N4P2 |
摩尔质量 | 580.6 g·mol−1 |
外观 | 无色晶体 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
双(三苯基膦)叠氮化亚铵是一种有机磷化合物,化学式为(C36H30NP2)N3。它可由氨基三苯基叠氮化鏻在200~210 °C热分解得到,[1]或由双(三苯基膦)氯化亚铵和碱金属叠氮化物的复分解反应制得。[2]它和氢溴酸或高氯酸反应,可以得到相应的溴化物或高氯酸盐。[1]它可用于制备一些叠氮配合物。[3]
参考文献
[编辑]- ^ 1.0 1.1 Cookson, R. C.; Hughes, A. N. Pyrolysis of triphenylphosphiniminium azide. Journal of the Chemical Society, 1963. pp 6061-6062. doi:10.1039/JR9630006039
- ^ Martinsen, Arve; Songstad, Jon. Preparation and properties of some bis(triphenylphosphine)iminium salts, [(Ph3P)2N]X. Acta Chemica Scandinavica, Series A: Physical and Inorganic Chemistry, 1977. 31 (8): 645-650. ISSN 0302-4377.
- ^ Haiges, Ralf; Rahm, Martin; Christe, Karl O. Unprecedented Conformational Variability in Main Group Inorganic Chemistry: the Tetraazidoarsenite and -Antimonite Salts A+[M(N3)4]− (A = NMe4, PPh4, (Ph3P)2N; M = As, Sb), Five Similar Salts, Five Different Anion Structures. Inorganic Chemistry (American Chemical Society (ACS)). 2012-12-07, 52 (1): 402–414. ISSN 0020-1669. doi:10.1021/ic3021996.