雙(三苯基膦)疊氮化亞銨
外觀
雙(三苯基膦)疊氮化亞銨 | |
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識別 | |
CAS號 | 38011-36-8 ![]() |
SMILES |
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性質 | |
化學式 | C36H30N4P2 |
摩爾質量 | 580.6 g·mol−1 |
外觀 | 無色晶體 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
雙(三苯基膦)疊氮化亞銨是一種有機磷化合物,化學式為(C36H30NP2)N3。它可由氨基三苯基疊氮化鏻在200~210 °C熱分解得到,[1]或由雙(三苯基膦)氯化亞銨和鹼金屬疊氮化物的複分解反應製得。[2]它和氫溴酸或高氯酸反應,可以得到相應的溴化物或高氯酸鹽。[1]它可用於製備一些疊氮配合物。[3]
參考文獻
[編輯]- ^ 1.0 1.1 Cookson, R. C.; Hughes, A. N. Pyrolysis of triphenylphosphiniminium azide. Journal of the Chemical Society, 1963. pp 6061-6062. doi:10.1039/JR9630006039
- ^ Martinsen, Arve; Songstad, Jon. Preparation and properties of some bis(triphenylphosphine)iminium salts, [(Ph3P)2N]X. Acta Chemica Scandinavica, Series A: Physical and Inorganic Chemistry, 1977. 31 (8): 645-650. ISSN 0302-4377.
- ^ Haiges, Ralf; Rahm, Martin; Christe, Karl O. Unprecedented Conformational Variability in Main Group Inorganic Chemistry: the Tetraazidoarsenite and -Antimonite Salts A+[M(N3)4]− (A = NMe4, PPh4, (Ph3P)2N; M = As, Sb), Five Similar Salts, Five Different Anion Structures. Inorganic Chemistry (American Chemical Society (ACS)). 2012-12-07, 52 (1): 402–414. ISSN 0020-1669. doi:10.1021/ic3021996.