氟硼酸锰

氟硼酸锰
识别
CAS号	30744-82-2
性质
化学式	Mn(BF4)2
密度	2.1 g·cm−3（六水）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

氟硼酸锰是一种无机化合物，化学式为Mn(BF₄)₂。它的水合物和氟硼酸三乙基𨦡在无水乙腈中反应，可以得到[Mn(CH₃CN)₄](BF₄)₂（这一化合物也可由Mn和NOBF₄反应得到）^[2]；和3(5)-甲基吡唑（MPZ）在原甲酸三乙酯存在下于乙醇中反应，可以得到Mn₄F₄(MPZ)₁₂(BF₄)₄。^[3]

六水合物[Mn(H₂O)₆](BF₄)₂在162 K和223 K发生相变。^[4]

参考文献[编辑]

^ K. C. Moss, D. R. Russell, D. W. A. Sharp. The lattice constants of some metal-fluoroborate hexahydrates. Acta Crystallographica. 1961-03-01, 14 (3): 330–330 [2022-06-22]. ISSN 0365-110X. doi:10.1107/S0365110X61001133. （原始内容存档于2022-06-22）.
^ Dimitri Coucouvanis (编). Useful Reagents and Ligands: Useful Reagents and Ligands. New York, USA: John Wiley & Sons, Inc. 2002-04-07: 75–121 [2022-06-22]. ISBN 9780471208259. doi:10.1002/0471224502.ch2. （原始内容存档于2022-06-08）.
^ Richard W.M. Ten Hoedt, Jan Reedijk. Synthesis, characterization and magnetic behaviour of tetra-μ3-fluorododecakis(5-methylpyrazole-N2)tetrametal(II) tetrakis(tetrafluoroborates). Inorganica Chimica Acta. 1981-01, 51: 23–27 [2022-06-22]. doi:10.1016/S0020-1693(00)88311-5. （原始内容存档于2018-06-07）（英语）.
^ E. Mikuli, A. Migdał-Mikuli, I. Natkaniec, B. Grad. Phase Transitions and Water Dynamics of [Co(H 2 O) 6 ](ClO 4 ) 2 and [Mn(H 2 O) 6 ](BF 4 ) 2 Studied by Neutron Scattering Methods. Zeitschrift für Naturforschung A. 2001-04-01, 56 (3-4): 244–248 [2022-06-22]. ISSN 1865-7109. doi:10.1515/zna-2001-0302. （原始内容存档于2022-06-22）（英语）.

[1] K. C. Moss, D. R. Russell, D. W. A. Sharp. The lattice constants of some metal-fluoroborate hexahydrates. Acta Crystallographica. 1961-03-01, 14 (3): 330–330 [2022-06-22]. ISSN 0365-110X. doi:10.1107/S0365110X61001133. （原始内容存档于2022-06-22）.

[2] Dimitri Coucouvanis (编). Useful Reagents and Ligands: Useful Reagents and Ligands. New York, USA: John Wiley & Sons, Inc. 2002-04-07: 75–121 [2022-06-22]. ISBN 9780471208259. doi:10.1002/0471224502.ch2. （原始内容存档于2022-06-08）.

[3] Richard W.M. Ten Hoedt, Jan Reedijk. Synthesis, characterization and magnetic behaviour of tetra-μ3-fluorododecakis(5-methylpyrazole-N2)tetrametal(II) tetrakis(tetrafluoroborates). Inorganica Chimica Acta. 1981-01, 51: 23–27 [2022-06-22]. doi:10.1016/S0020-1693(00)88311-5. （原始内容存档于2018-06-07）（英语）.

[4] E. Mikuli, A. Migdał-Mikuli, I. Natkaniec, B. Grad. Phase Transitions and Water Dynamics of [Co(H 2 O) 6 ](ClO 4 ) 2 and [Mn(H 2 O) 6 ](BF 4 ) 2 Studied by Neutron Scattering Methods. Zeitschrift für Naturforschung A. 2001-04-01, 56 (3-4): 244–248 [2022-06-22]. ISSN 1865-7109. doi:10.1515/zna-2001-0302. （原始内容存档于2022-06-22）（英语）.

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