烯丙胺盐酸盐

添加链接
维基百科，自由的百科全书
烯丙胺盐酸盐
识别
CAS号 10017-11-5  checkY
性质
化学式 C3H8ClN
摩尔质量 93.56 g·mol−1
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

烯丙胺盐酸盐是烯丙胺和氯化氢形成的盐，化学式为C3H8NCl。它可用于聚烯丙胺（德语：Polyallylamin）或聚烯丙胺盐酸盐（英语：Polyallylamine hydrochloride）的合成。[1]

制备及反应[编辑]

烯丙胺盐酸盐可由烯丙胺和盐酸在5 °C反应得到，在60 °C可整去大部分溶剂，然后在−80 °C冻干，得到固体。[2]N-Boc-烯丙胺和氯化氢反应，也能得到烯丙胺盐酸盐。[3]N,N-二(三甲基硅基)烯丙胺和盐酸反应，也能得到该产物。[4]

它在含次磷酸的氢碘酸中煮沸反应，可以得到2-碘丙胺氢碘酸盐。这一反应在常温下不会发生。[5]它和氰酸钾在水中加热反应，可以得到烯丙基脲。[6]它和硫脲在苯甲醚中于180 °C反应，可以得到烯丙基异硫氰酸酯。[7]

参考文献[编辑]

  1. ^ Hiroaki Oie, Atsushi Sudo, Takeshi Endo. Synthesis of polymers bearing 1,3-benzoxazine moiety in the side chains from poly(allylamine) and their crosslinking behaviors. Journal of Polymer Science Part A: Polymer Chemistry. 2011-07-15, 49 (14): 3174–3183 [2022-05-02]. doi:10.1002/pola.24754. （原始内容存档于2022-05-02） （英语）. 
  2. ^ H. Iván Meléndez-Ortiz, Bertha Puente-Urbina, Griselda Castruita-de León, Jesus Alfonso Mercado-Silva, Esmeralda Saucedo-Salazar, Luis Alfonso García-Cerda. Covalent attachment of poly(allylamine hydrochloride) onto ordered silica foams. Journal of Porous Materials. 2020-06, 27 (3): 929–937 [2022-05-02]. ISSN 1380-2224. doi:10.1007/s10934-020-00870-8 （英语）. 
  3. ^ Rik H. Verschueren, Philippe Gilles, Seger Van Mileghem, Wim M. De Borggraeve. Solvent-free N -Boc deprotection by ex situ generation of hydrogen chloride gas. Organic & Biomolecular Chemistry. 2021, 19 (26): 5782–5787 [2022-05-02]. ISSN 1477-0520. doi:10.1039/D1OB00728A （英语）. 
  4. ^ Bestmann, Hans Juergen; Woelfel, Gerhard. Simple synthesis of primary amines via their N,N-bis(trimethylsilyl) derivatives. Chemische Berichte, 1984. 117 (3): 1250-1254. ISSN 0009-2940.
  5. ^ Eugenia S. Vasileiadou, Xinyi Jiang, Mikaël Kepenekian, Jacky Even, Michael C. De Siena, Vladislav V. Klepov, Daniel Friedrich, Ioannis Spanopoulos, Qing Tu, Imra S. Tajuddin, Emily A. Weiss, Mercouri G. Kanatzidis. Thick-Layer Lead Iodide Perovskites with Bifunctional Organic Spacers Allylammonium and Iodopropylammonium Exhibiting Trap-State Emission. Journal of the American Chemical Society. 2022-04-13, 144 (14): 6390–6409 [2022-05-02]. ISSN 0002-7863. doi:10.1021/jacs.2c00571. （原始内容存档于2022-05-02） （英语）. 
  6. ^ Ya Gao, Jinshan Xie, Ruotian Tang, Kaiyin Yang, Yahan Zhang, Lixia Chen, Hua Li. Identification of a pyrimidinetrione derivative as the potent DprE1 inhibitor by structure-based virtual ligand screening. Bioorganic Chemistry. 2019-04, 85: 168–178 [2022-05-02]. doi:10.1016/j.bioorg.2018.12.018 （英语）. 
  7. ^ Shinohata, Masaaki; Kosugi, Yuji; Miyake, Nobuhisa. Method for preparation of isothiocyanates and storing the intermediates thiocarbamates. 2014 WO 2014136690 A1.
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