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苊钠

维基百科,自由的百科全书
苊钠
英文名 Sodium acenaphthalenide
识别
CAS号 34516-23-9  checkY
相关物质
其他阴离子 环戊二烯基钠
萘钠
腈钠
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

苊钠是一种有机化合物,可由金属四氢呋喃中反应得到。[1]苊钠是一种还原剂,如可以将六价钼的氢三(3-异丙基吡唑-1-基)硼酸盐配合物还原为五价:[2]

Na(Acn) + LMoVIO2(SPh) + PPh4Cl → Acn + PPh4[LMoVO2(SPh)] + NaCl

相关化合物苊钾也有报道。[3]

参考文献

[编辑]
  1. ^ G. Christou, K. S. Hagen, J. K. Bashkin, R. H. Holm. The clusters [Co8S6(SPh)8]4-,5-: preparations, properties, and structural relationship of near-cubic Co8(.mu.4-S)6 cores to the clusters in synthetic pentlandite. Inorganic Chemistry. 1985-03, 24 (7): 1010–1018 [2018-07-23]. ISSN 0020-1669. doi:10.1021/ic00201a010. (原始内容存档于2019-10-16) (英语). 
  2. ^ Zhiguang Xiao, Robert W. Gable, Anthony G. Wedd, Charles G. Young. Complexes Containingcis-[MoVO2]+andcis-[MoVO(OH)]2+Centers. Journal of the American Chemical Society. 1996-01, 118 (12): 2912–2921 [2018-07-23]. ISSN 0002-7863. doi:10.1021/ja952525a. (原始内容存档于2019-10-13) (英语). 
  3. ^ Joseph J. Maj, A. David Rae, Lawrence F. Dahl. Experimental analysis of the antibonding trimetal character of the HOMO in the paramagnetic Fischer-Palm Ni3(.eta.5-C5H5)3(.mu.3-CO)2 cluster: synthesis and stereochemical characterization of the electronically equivalent [(.eta.5-C5Me5)CoNi2(.eta.5-C5H5)2(.mu.3-CO)2]- monoanion and neutral Ni3(.eta.5-C5Me5)3(.mu.3-CO)2 analog and of the [Ni3(.eta.5-C5H5)3(.mu.3-CO)2]- monoanion. Journal of the American Chemical Society. 1982-06, 104 (11): 3054–3063 [2018-07-23]. ISSN 0002-7863. doi:10.1021/ja00375a019. (原始内容存档于2019-10-09) (英语).