2,2'-二苯醚二甲酸
外观
2,2'-二苯醚二甲酸 | |
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英文名 | 2,2'-oxybisbenzoic acid |
别名 | 2,2'-二羧基二苯醚 |
识别 | |
CAS号 | 37424-29-6 ![]() |
SMILES |
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性质 | |
化学式 | C14H10O5 |
摩尔质量 | 258.23 g·mol⁻¹ |
熔点 | 230 °C(503 K)[1] |
溶解性(水) | 6.7 g[2] |
pKa | 2.96±0.36[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
2,2'-二苯醚二甲酸是一种有机化合物,化学式为C14H10O5。它可由二苯醚和二氧化碳、丁基锂反应得到。[3]也可由邻溴甲苯和邻甲基苯酚为原料反应得到。[4]含侧链邻位甲基二苯醚经氧化后生成该有机物。[5]它可以和铜、镉等金属形成配位化合物。[6]
参考文献
[编辑]- ^ Richard H. F. Manske, Archie E. Ledingham. Synthesis and Reactions of Some Dibenzoxepins. Journal of the American Chemical Society. 1950-10, 72 (10): 4797–4799 [2018-09-22]. ISSN 0002-7863. doi:10.1021/ja01166a128. (原始内容存档于2019-04-11) (英语).
- ^ 2.0 2.1 Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2018 ACD/Labs). Retrieved from SciFinder. [2018-9-22]
- ^ Heinz W. Gschwend, Herman R. Rodriguez. Heteroatom-Facilitated Lithiations. American Cancer Society. 2005: 1–360 [2018-12-04]. ISBN 9780471264187. doi:10.1002/0471264180.or026.01 (英语).
- ^ Voegtle, Fritz; Kleiner, Thomas; Leppkes, Reinhard; Laeubli, Markus Werner; Ammann, Daniel; Simon, Wilhelm. Neutral ionophores with selectivity for sodium ion. Chemische Berichte, 1983. 116 (5): 2028-2034.
- ^ Hellwinkel, Dieter; Bohnet, Siegbert. Dibenzocyclooctene-, dibenzochalcocine-, and diarenochalconinediones. Chemische Berichte, 1987. 120 (7). 1151-1173.
- ^ Bi-Feng Huang, Tian Sun, Zahra Sharifzadeh, Meng-Yi Lv, Hong-Ping Xiao, Xin-Hua Li, Ali Morsali. Multinuclear coordination polymers constructed from V-shaped multicarboxylate and bis(imidazol-1-ylmethyl)-benzene ligand: Syntheses, crystal structures, and luminescent properties. Inorganica Chimica Acta. 2013-08, 405: 83–90 [2018-09-22]. ISSN 0020-1693. doi:10.1016/j.ica.2013.05.019. (原始内容存档于2020-02-29).