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2,2'-二(三氟甲基)联苯

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维基百科，自由的百科全书
2,2'-二(三氟甲基)联苯
识别
CAS号 567-15-7  checkY
SMILES
 
  • FC(F)(F)C=1C=CC=CC1C=2C=CC=CC2C(F)(F)F
性质
化学式 C14H8F6
摩尔质量 290.2 g·mol−1
熔点 32 °C（305 K）[1]
沸点 230 °C（503 K）[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

2,2'-二(三氟甲基)联苯是一种有机化合物，化学式为C14H8F6，它可由2-三氟甲基卤苯[2][3]或2-三氟甲基苯硼酸[4]的偶联反应制得，或由联苯-2,2'-二甲酸和1-三氟硫基-2,6-二甲基-4-叔丁基苯反应得到。[5]它和混酸发生硝化反应，生成2,2'-二(三氟甲基)-4,4'-二硝基联苯。[6]

参考文献

[编辑]
  1. ^ 1.0 1.1 R. A. Cartwright, J. C. Tatlow. 406. The reactions of certain nitrogen-containing compounds derived from benzotrifluoride. Journal of the Chemical Society (Resumed). 1953: 1994 [2021-03-20]. ISSN 0368-1769. doi:10.1039/jr9530001994 （英语）. 
  2. ^ Gosmini, Corinne; Moncomble, Aurelien. Cobalt bromide. e-EROS Encyclopedia of Reagents for Organic Synthesis, 2011. 1-8. ISBN 978-0-470-84289-8.
  3. ^ Todd D. Nelson, R. David Crouch. John Wiley & Sons, Inc. , 编. Cu, Ni, and Pd Mediated Homocoupling Reactions in Biaryl Syntheses: The Ullmann Reaction. Hoboken, NJ, USA: John Wiley & Sons, Inc. 2004-01-28: 265–555 [2021-03-20]. ISBN 9780471264187. doi:10.1002/0471264180.or063.03 （英语）. 
  4. ^ Zhonggao Zhou, Jing Li, Yue Wu, Yangyang Yuan, Lingfang Kong, Jun Xue, Zhiqiang Huang. Glucopyranoside-substituted imidazolium-based chiral ionic liquids for Pd-catalyzed homo-coupling of arylboronic acids in water. Journal of Carbohydrate Chemistry. 2020-07-23, 39 (5-6): 288–299 [2021-03-20]. ISSN 0732-8303. doi:10.1080/07328303.2020.1788573 （英语）. 
  5. ^ Teruo Umemoto, Rajendra P. Singh, Yong Xu, Norimichi Saito. Discovery of 4- tert -Butyl-2,6-dimethylphenylsulfur Trifluoride as a Deoxofluorinating Agent with High Thermal Stability as Well as Unusual Resistance to Aqueous Hydrolysis, and Its Diverse Fluorination Capabilities Including Deoxofluoro-Arylsulfinylation with High Stereoselectivity. Journal of the American Chemical Society. 2010-12-29, 132 (51): 18199–18205 [2021-03-20]. ISSN 0002-7863. doi:10.1021/ja106343h. （原始内容存档于2020-11-10） （英语）. 
  6. ^ Nozoe, Tatsuhiro; Nakaya, Masao. Industrial preparation of trifluoromethyl-substituted biphenyl derivatives. 2008. JP 2008255037 A.
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