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丁炔二酸二乙酯

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丁炔二酸二乙酯
识别
CAS号 762-21-0  checkY
性质
化学式 C8H10O4
摩尔质量 170.16 g·mol−1
熔点 1.5 °C[1]
沸点 108~118 °C(10 torr)[2]
相关物质
相关化学品 丁炔二酸
丁炔二酸二甲酯
马来酸二乙酯
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

丁炔二酸二乙酯是一种不饱和羧酸酯,化学式为C8H10O4,它可由丁炔二酸乙醇硫酸催化下反应得到。[3]它在镍钯合金催化下加氢,可以得到丁二酸二乙酯[4]它和其它炔烃一样,可以发生聚合反应,它自身三聚得到苯六甲酸六乙酯。[5]

参考文献

[编辑]
  1. ^ "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-09-20].
  2. ^ J. F. Grove. The Fungistatic Activity of Ethylenic and Acetylenic Compounds.: Esters of Halogenofumaric Acids and Acetylene Dicarboxylic Acid. Annals of Applied Biology. 1948-03, 35 (1): 37–44 [2021-09-20]. ISSN 0003-4746. doi:10.1111/j.1744-7348.1948.tb07348.x (英语). 
  3. ^ William E. Truce, Robert B. Kruse. The Stereochemistry of the Base-catalyzed Addition of p-Toluenethiol to Disodium and Diethyl Acetylenedicarboxylate 1,2. Journal of the American Chemical Society. 1959-10, 81 (20): 5372–5374 [2021-09-20]. ISSN 0002-7863. doi:10.1021/ja01529a030 (英语). 
  4. ^ Yasin Çetinkaya, Önder Metin, Metin Balci. Reduced graphene oxide supported nickel–palladium alloy nanoparticles as a superior catalyst for the hydrogenation of alkenes and alkynes under ambient conditions. RSC Advances. 2016, 6 (34): 28538–28542 [2021-09-20]. ISSN 2046-2069. doi:10.1039/C5RA25376D (英语). 
  5. ^ Nicolas Agenet, Olivier Buisine, Franck Slowinski, Vincent Gandon, Corinne Aubert, Max Malacria. John Wiley & Sons, Inc. , 编. Cotrimerizations of Acetylenic Compounds. Hoboken, NJ, USA: John Wiley & Sons, Inc. 2007-03-12: 1–302 [2021-09-20]. ISBN 9780471264187. doi:10.1002/0471264180.or068.01. (原始内容存档于2022-03-08) (英语).