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4-巯基苯酚

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4-巯基苯酚
别名 4-羟基苯硫酚
识别
CAS号 637-89-8  checkY
性质
化学式 C6H6OS
摩尔质量 126.18 g·mol−1
熔点 30 °C(303 K)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

4-巯基苯酚是一种有机硫化合物,化学式为HSC6H4OH。它可以4-碘苯酚乙二硫醇为原料反应制得。[2]它可以被氧化为二(4-羟基苯基)二硫化物。[3]它和2,5-二溴-1,4-苯二腈在碳酸钾存在下于DMF中反应,可以得到2,5-二(4-羟基苯硫基)-1,4-苯二腈。[4]

参考文献

[编辑]
  1. ^ Iovu, Mircea; Badau, Elena. Benzyloxyphenyl benzyl sulfides. Revistade Chimie (Bucharest, Romania), 1984. 35 (10): 881-887. ISSN 0034-7752.
  2. ^ Yajun Liu, Jihye Kim, Heesun Seo, Sunghyouk Park, Junghyun Chae. Copper(II)-Catalyzed Single-Step Synthesis of Aryl Thiols from Aryl Halides and 1,2-Ethanedithiol. Advanced Synthesis & Catalysis. 2015-07-06, 357 (10): 2205–2212 [2022-10-04]. doi:10.1002/adsc.201400941. (原始内容存档于2022-10-07) (英语). 
  3. ^ Owen, David Alan; Montana, John Gary; Keily, John Fraser; Watson, Robert John; Baxter, Andrew Douglas. Preparation of hydroxamic and carboxylic acid derivatives having MMP and TNF inhibitory activity. 2003 US 6566384 B1.
  4. ^ Riebe, Steffen; Vallet, Cecilia; van der Vight, Felix; Gonzalez-Abradelo, Dario; Wölper, Christoph; Strassert, Cristian A.; Jansen, Georg; Knauer, Shirley; Voskuhl, Jens. Aromatic Thioethers as Novel Luminophores with Aggregation-Induced Fluorescence and Phosphorescence. Chemistry - A European Journal. 9 August 2017, 23 (55): 13660–13668. ISSN 0947-6539. PMID 28661014. doi:10.1002/chem.201701867.