聯苯-4-硫酚
外觀
聯苯-4-硫酚 | |
---|---|
別名 | 4-苯基苯硫酚 4-巰基聯苯 |
識別 | |
CAS號 | 19813-90-2 |
性質 | |
化學式 | C12H10S |
摩爾質量 | 186.27 g·mol−1 |
熔點 | 111—112 °C(384—385 K)[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
聯苯-4-硫酚是一種有機硫化合物,化學式為C12H10S。它可由苯硼酸和4-碘苯硫酚在催化下反應製得,[2]或通過4-碘聯苯和硫化鈉在銅、乙二硫醇催化下於DMSO中加熱反應得到。[3]
反應
[編輯]聯苯-4-硫酚和三氟甲磺酰基苯在碳酸銫存在下反應,可以得到4-三氟甲硫基聯苯。[4]
參考文獻
[編輯]- ^ L. Testaferri, M. Tiecco, M. Tingoli, D. Chianelli, M. Montanucci. Simple Syntheses of Aryl Alkyl Thioethers and of Aromatic Thiols from Unactivated Aryl Halides and Efficient Methods for Selective Dealkylation of Aryl Alkyl Ethers and Thioethers. Synthesis. 1983, 1983 (09): 751–755 [2022-09-17]. ISSN 0039-7881. doi:10.1055/s-1983-30501. (原始內容存檔於2018-06-04) (英語).
- ^ Yaran Zhao, Lili Du, Haixia Li, Wei Xie, Jun Chen. Is the Suzuki–Miyaura Cross-Coupling Reaction in the Presence of Pd Nanoparticles Heterogeneously or Homogeneously Catalyzed? An Interfacial Surface-Enhanced Raman Spectroscopy Study. The Journal of Physical Chemistry Letters. 2019-03-21, 10 (6): 1286–1291 [2022-09-17]. ISSN 1948-7185. doi:10.1021/acs.jpclett.9b00351. (原始內容存檔於2022-09-22) (英語).
- ^ Hongyu Xue, Bing Jing, Shasha Liu, Junghyun Chae, Yajun Liu. Copper-Catalyzed Direct Synthesis of Aryl Thiols from Aryl Iodides Using Sodium Sulfide Aided by Catalytic 1,2-Ethanedithiol. Synlett. 2017-10, 28 (17): 2272–2276 [2022-09-17]. ISSN 0936-5214. doi:10.1055/s-0036-1588482. (原始內容存檔於2018-06-07) (英語).
- ^ Zhiqiang Wei, Zhengzhao Lou, Chuanfa Ni, Wei Zhang, Jinbo Hu. Visible-light-promoted S -trifluoromethylation of thiophenols with trifluoromethyl phenyl sulfone. Chemical Communications. 2022, 58 (72): 10024–10027 [2022-09-17]. ISSN 1359-7345. doi:10.1039/D2CC03921D (英語).
- ^ Zhen Wang, Yoichiro Kuninobu, Motomu Kanai. Molybdenum-Mediated Desulfurization of Thiols and Disulfides. Synlett. 2014-06-06, 25 (13): 1869–1872 [2022-09-17]. ISSN 0936-5214. doi:10.1055/s-0034-1378315. (原始內容存檔於2018-06-03) (英語).