四(1-降冰片基)鐵

四(1-降冰片基)鐵
別名	Tetrakis(bicyclo[2.2.1]hept-1-yl)iron; Tetra(1-norbornyl)iron
識別
CAS號	36409-79-7
性質
化學式	C28H44Fe
摩爾質量	436.49 g·mol−1
外觀	紫色晶體
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

四(1-降冰片基)鐵是一種有機鐵化合物，化學式為C₂₈H₄₄Fe，可簡寫為Nor₄Fe。它可由三氯化鐵乙醚合物和1-降冰片基鋰反應得到。^[1]^[2]在該反應中，Fe^III會被還原為Fe^II，並產生1,1'-聯降冰片烷，然後Fe^II在與NorLi反應的過程中，歧化為Fe^IV和單質鐵：^[3]

2 FeCl₃ + 6 NorLi → Nor₄Fe + Fe + 6 LiCl + Nor-Nor

它不穩定，室溫時即可分解。^[1]

參考文獻[編輯]

^ ^1.0 ^1.1 ^1.2 Bower, Barton K.; Tennent, Howard G. Transition metal bicyclo[2.2.1]hept-1-yls. Journal of the American Chemical Society. 2002, 94 (7): 2512–2514. ISSN 0002-7863. doi:10.1021/ja00762a056.
^ Thiele, Karl Heinz; Dimitrov, Vladimir; Schenke, Detlef; Krueger, Annekatrin; Rusina, Albert. 1-Norbornyl compounds of tetravalent 3d transition metals（德文）. Wissenschaftliche Zeitschrift der Technischen Hochschule Carl Schorlemmer Leuna-Merseburg, 1986. 28 (2): 197-202. ISSN: 0323-5270.
^ Richard A. Lewis, Danil E. Smiles, Jonathan M. Darmon, S. Chantal E. Stieber, Guang Wu, Trevor W. Hayton. Reactivity and Mössbauer Spectroscopic Characterization of an Fe(IV) Ketimide Complex and Reinvestigation of an Fe(IV) Norbornyl Complex. Inorganic Chemistry. 2013-07-15, 52 (14): 8218–8227 [2021-08-03]. ISSN 0020-1669. doi:10.1021/ic401096p. （原始內容存檔於2021-08-03）（英語）.

[Bower-1] 1.0 ^1.1 ^1.2 Bower, Barton K.; Tennent, Howard G. Transition metal bicyclo[2.2.1]hept-1-yls. Journal of the American Chemical Society. 2002, 94 (7): 2512–2514. ISSN 0002-7863. doi:10.1021/ja00762a056.

[2] Thiele, Karl Heinz; Dimitrov, Vladimir; Schenke, Detlef; Krueger, Annekatrin; Rusina, Albert. 1-Norbornyl compounds of tetravalent 3d transition metals（德文）. Wissenschaftliche Zeitschrift der Technischen Hochschule Carl Schorlemmer Leuna-Merseburg, 1986. 28 (2): 197-202. ISSN: 0323-5270.

[3] Richard A. Lewis, Danil E. Smiles, Jonathan M. Darmon, S. Chantal E. Stieber, Guang Wu, Trevor W. Hayton. Reactivity and Mössbauer Spectroscopic Characterization of an Fe(IV) Ketimide Complex and Reinvestigation of an Fe(IV) Norbornyl Complex. Inorganic Chemistry. 2013-07-15, 52 (14): 8218–8227 [2021-08-03]. ISSN 0020-1669. doi:10.1021/ic401096p. （原始內容存檔於2021-08-03）（英語）.

[1]

[2]

[3]