四(1-降冰片基)铁

四(1-降冰片基)铁
别名	Tetrakis(bicyclo[2.2.1]hept-1-yl)iron; Tetra(1-norbornyl)iron
识别
CAS号	36409-79-7
性质
化学式	C28H44Fe
摩尔质量	436.49 g·mol−1
外观	紫色晶体
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

四(1-降冰片基)铁是一种有机铁化合物，化学式为C₂₈H₄₄Fe，可简写为Nor₄Fe。它可由三氯化铁乙醚合物和1-降冰片基锂反应得到。^[1]^[2]在该反应中，Fe^III会被还原为Fe^II，并产生1,1'-联降冰片烷，然后Fe^II在与NorLi反应的过程中，歧化为Fe^IV和单质铁：^[3]

2 FeCl₃ + 6 NorLi → Nor₄Fe + Fe + 6 LiCl + Nor-Nor

它不稳定，室温时即可分解。^[1]

参考文献

^ ^1.0 ^1.1 ^1.2 Bower, Barton K.; Tennent, Howard G. Transition metal bicyclo[2.2.1]hept-1-yls. Journal of the American Chemical Society. 2002, 94 (7): 2512–2514. ISSN 0002-7863. doi:10.1021/ja00762a056.
^ Thiele, Karl Heinz; Dimitrov, Vladimir; Schenke, Detlef; Krueger, Annekatrin; Rusina, Albert. 1-Norbornyl compounds of tetravalent 3d transition metals（德文）. Wissenschaftliche Zeitschrift der Technischen Hochschule Carl Schorlemmer Leuna-Merseburg, 1986. 28 (2): 197-202. ISSN: 0323-5270.
^ Richard A. Lewis, Danil E. Smiles, Jonathan M. Darmon, S. Chantal E. Stieber, Guang Wu, Trevor W. Hayton. Reactivity and Mössbauer Spectroscopic Characterization of an Fe(IV) Ketimide Complex and Reinvestigation of an Fe(IV) Norbornyl Complex. Inorganic Chemistry. 2013-07-15, 52 (14): 8218–8227 [2021-08-03]. ISSN 0020-1669. doi:10.1021/ic401096p. （原始内容存档于2021-08-03）（英语）.

[Bower-1] 1.0 ^1.1 ^1.2 Bower, Barton K.; Tennent, Howard G. Transition metal bicyclo[2.2.1]hept-1-yls. Journal of the American Chemical Society. 2002, 94 (7): 2512–2514. ISSN 0002-7863. doi:10.1021/ja00762a056.

[2] Thiele, Karl Heinz; Dimitrov, Vladimir; Schenke, Detlef; Krueger, Annekatrin; Rusina, Albert. 1-Norbornyl compounds of tetravalent 3d transition metals（德文）. Wissenschaftliche Zeitschrift der Technischen Hochschule Carl Schorlemmer Leuna-Merseburg, 1986. 28 (2): 197-202. ISSN: 0323-5270.

[3] Richard A. Lewis, Danil E. Smiles, Jonathan M. Darmon, S. Chantal E. Stieber, Guang Wu, Trevor W. Hayton. Reactivity and Mössbauer Spectroscopic Characterization of an Fe(IV) Ketimide Complex and Reinvestigation of an Fe(IV) Norbornyl Complex. Inorganic Chemistry. 2013-07-15, 52 (14): 8218–8227 [2021-08-03]. ISSN 0020-1669. doi:10.1021/ic401096p. （原始内容存档于2021-08-03）（英语）.

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